Synthesis and characterisation of new pyrazole–phosphinite ligands and their ruthenium (II) arene complexes

R Tribó, S Muñoz, J Pons, R Yáñez… - Journal of …, 2005 - Elsevier
The new potentially bidentate pyrazole–phosphinite ligands [(3, 5-dimethyl-1H-pyrazol-1-yl)
methyl diphenylphosphinite](L1) and [2-(3, 5-dimethyl-1H-pyrazol-1-yl) ethyl …

Enantioselective transfer hydrogenation of various ketones with novel efficient iridium (III) ferrocenyl-phosphinite catalysts

N Meric, M Aydemir - Journal of Organometallic Chemistry, 2016 - Elsevier
The asymmetric reduction of prochiral ketones is a pivotal reaction for the preparation of
chiral alcohols which form an extremely important class of intermediates for fine chemicals …

Coordination compounds of Cd (II) with several bidentate-NN′ and tridentate-NN′ N nitrogen donor ligands. 113Cd NMR studies of monomeric compounds …

J Pons, J García-Antón, M Font-Bardia, T Calvet… - Inorganica Chimica …, 2009 - Elsevier
Reaction of CdCl2 with N-alkylaminopyrazole ligands 1-[(2-ethylamino) ethyl]-3, 5-
dimethylpyrazole (deae), 1-[(2-(tert-butylamino) ethyl)]-3, 5-dimethylpyrazole (deat), bis-[(3 …

Synthesis and characterization of metallomacrocyclic palladium (II) complexes with new hybrid pyrazole ligands. Diffusion NMR studies and theoretical calculations

M Guerrero, J Pons, V Branchadell, T Parella… - Inorganic …, 2008 - ACS Publications
Three new 3, 5-dimethylpyrazolic hybrid ligands N1-substituted by polyether chains and
phenyl groups have been synthesized: 1, 2-bis [4-(3, 5-dimethyl-1 H-pyrazol-1-yl)-2 …

Synthesis, spectroscopic properties and structural characterisation of Pd (II) and Pt (II) complexes with 1, 3, 5-pyrazole derived ligands. Rotation around the metal–N …

V Montoya, J Pons, X Solans, M Font-Bardia… - Inorganica chimica acta, 2005 - Elsevier
Reactions of ligands 1-ethyl-5-methyl-3-phenyl-1H-pyrazole (L1) and 5-methyl-1-octyl-3-
phenyl-1H-pyrazole (L2) with [PdCl2 (CH3CN) 2 and K2PtCl4 gave complexes trans-[MCl2 …

The application of tunable tridendate P‐based ligands for the Ru (II)‐catalysed transfer hydrogenation of various ketones

N Meriç, F Durap, M Aydemir… - Applied Organometallic …, 2014 - Wiley Online Library
Two novel versatile tridendate aminophosphine–phosphinite and phosphinite ligands were
prepared and their trinuclear neutral ruthenium (II) dichloro complexes were found to be …

Synthesis, X-ray crystal structure, and NMR characterisation of thiolate-bridged dinuclear Ni (II), Pd (II) and Pt (II) complexes of didentate ligands with NS-donor set

J Garcı́a-Antón, J Pons, X Solans, M Font-Bardia… - Inorganica chimica …, 2003 - Elsevier
Thiolate-bridged dinuclear nickel (II), palladium (II) and platinum (II) complexes with N-(2-
mercaptoethyl)-3, 5-dimethylpyrazole (Hmed),[MCl (med)] 2 (M= Ni (1), Pd (2), Pt (3)), have …

Synthesis of ionic liquid-based Ru (II)–phosphinite complexes and evaluation of their antioxidant, antibacterial, DNA-binding, and DNA cleavage activities

N Meriç, C Kayan, K Rafikova, A Zazybin, V Okumuş… - Chemical Papers, 2019 - Springer
Two Ru (II) complexes were synthesized by reaction of phosphinite-functionalized
imidazolium salts [(Ph 2 PO) C 7 H 11 N 2 Cl] Cl (1) and [(Cy 2 PO) C 7 H 11 N 2 Cl] Cl (2) …

Six-coordinate alkynyldiphenylphosphine ruthenium (II) complexes: Synthesis, structure, and catalytic activity as ROMP initiators

M Bernechea, N Lugan, B Gil, E Lalinde… - …, 2006 - ACS Publications
Six-coordinate [trans-RuCl2 (PPh2C⋮ CR) 4](R= Ph (1),(4-CH3) C6H4 (2),(4-OCH3)
C6H4,(3),(4-CF3) C6H4 (4)) were obtained from the reaction of RuCl3⊙ x H2O with the …

Synthesis of Ru (II) complexes of the new 1-[(P-diphenyl)-2-phosphinoethyl]-3, 5-dimethylpyrazole ligand and study of their reactivity toward terminal alkynes

G Esquius, J Pons, R Yáñez, J Ros, R Mathieu… - Journal of …, 2003 - Elsevier
The reaction between [RuCl2 (PPh3) 3] and one or two equivalent amounts of 1-[(P-
diphenyl)-2-phosphinoethyl]-3, 5-dimethylpyrazole (1) in dichloromethane gave [RuCl2 …