Visible light‐induced Pd catalysis has emerged as a promising subfield of photocatalysis.
The hybrid nature of Pd radical species has enabled a wide array of radical‐based …

Metallaphotoredox catalysis merging photocatalysis and transition metal catalysis is now the
most efficient platform for sp 3 C–H functionalizations due to its very efficient activation and …

Unveiling the alkyl/Pd hybrid species is a unique sp3-C-centered radical for facilitating
intermolecular hydrogen atom transfer (HAT) in the development of direct alkylation of …

Abstract Photocatalytic selective C (sp3)–H activation/cross-coupling reactions are
appealing in organic synthesis. In this manuscript, we describe the development of …

Alkyl radicals generated via an acridine photocatalyzed decarboxylation reaction of
feedstock carboxylic acids engage with a range of cyclic imine–BF3 complexes to provide α …

The reaction of organozinc reagents with unactivated imines is accelerated when performed
in the presence of a photocatalyst under blue light irradiation. Coordination between Lewis …

The development of excited-state palladium-catalyzed alkylative cyclization of acrylamides
and the alkylation of quinoxalinones is described. The application of a variety of primary …

Palladium-catalyzed chemical reactions play an important role in organic synthesis. On the
other hand, visible light induced reactions can achieve many chemical transformations …

Photoinduced Pd‐catalyzed bisfunctionalization of butadienes with a readily available
organic halide and a nucleophile represents an emerging and attractive method to …

The C (sp3)–N bond is ubiquitous in natural products, pharmaceuticals, biologically active
molecules and functional materials. Consequently, the development of practical and efficient …