Iridium-catalyzed C–H activation and borylation has become as a powerful synthetic tool in
the past few decades because of the widespread applicability and versatility of organoboron …

Catalysts that distinguish between electronically distinct carbon-hydrogen (C–H) bonds
without relying on steric effects or directing groups are challenging to design. In this work …

Pd‐catalysis has stood as a pivotal force in synthetic transformations for decades,
maintaining its status as a paramount tool in the realm of C− H bond activation. While …

The discovery of milder and robust strategies to enable the introduction of organoboronates
in peptides remains conspicuously underdeveloped. Herein, we demonstrate an efficient …

Traditional reaction conditions in Ir-catalyzed C–H borylation consist of a 2: 1 ligand to Ir
metal ratio, affording C (sp2)–H borylation at the least sterically hindered position. We found …

Exploitation of noncovalent interactions for recognition of an organic substrate has received
much attention for the design of metal catalysts in organic synthesis. The CH–π interaction is …

Herein, the selective ortho‐and meta‐C− H bond borylation of NH‐aryl sulfoximines is
reported. Regioselectivity is achieved by the choice of commercially available ligands giving …

Remote functionalization through progressive olefin isomerization enables site-selective
modification at a distal position, diversifying the synthetic approaches. However, the …

The indole moiety is ubiquitous in natural products and pharmaceuticals. C–H borylation of
the benzenoid moiety of indoles is a challenging task, especially at the C5 position. We have …

Direct functionalization of 1, 2-azaborines to construct B–C bonds remains challenging.
Here, we report a Pd-catalyzed B–H aryl/alkenylation reaction of 1, 2-azaborines. The …