Group 16 conjugated polymers based on furan, thiophene, selenophene, and tellurophene

S Ye, V Lotocki, H Xu, DS Seferos - Chemical Society Reviews, 2022 - pubs.rsc.org
Five-membered aromatic rings containing Group 16 elements (O, S, Se, and Te), also
referred as chalcogenophenes, are ubiquitous building blocks for π-conjugated polymers …

Kumada Catalyst‐Transfer Polycondensation: Mechanism, Opportunities, and Challenges

A Kiriy, V Senkovskyy, M Sommer - Macromolecular rapid …, 2011 - Wiley Online Library
Kumada catalyst‐transfer polycondensation (KCTP) is a new but rapidly developing method
with great potential for the preparation of well‐defined conjugated polymers (CPs). The …

A broadly applicable strategy for entry into homogeneous nickel (0) catalysts from air-stable nickel (II) complexes

EA Standley, SJ Smith, P Müller, TF Jamison - Organometallics, 2014 - ACS Publications
A series of air-stable nickel complexes of the form L2Ni (aryl) X (L= monodentate phosphine,
X= Cl, Br) and LNi (aryl) X (L= bis-phosphine) have been synthesized and are presented as …

On the role of single regiodefects and polydispersity in regioregular poly (3-hexylthiophene): defect distribution, synthesis of defect-free chains, and a simple model for …

P Kohn, S Huettner, H Komber… - Journal of the …, 2012 - ACS Publications
Identifying structure formation in semicrystalline conjugated polymers is the fundamental
basis to understand electronic processes in these materials. Although correlations between …

Conjugated polymer synthesis via catalyst-transfer polycondensation (CTP): mechanism, scope, and applications

ZJ Bryan, AJ McNeil - Macromolecules, 2013 - ACS Publications
The recent discovery of a living, controlled chain-growth method for synthesizing π-
conjugated polymers has ignited the field and led to the development of many new …

Controlled polymerizations for the synthesis of semiconducting conjugated polymers

K Okamoto, CK Luscombe - Polymer Chemistry, 2011 - pubs.rsc.org
Conjugated polymers have been under active development since the 1970s as the active
material in organic field-effect transistors (OFETs), photovoltaic devices and the emissive …

Toward perfect control of end groups and polydispersity in poly (3-hexylthiophene) via catalyst transfer polymerization

RH Lohwasser, M Thelakkat - Macromolecules, 2011 - ACS Publications
We report the influence of the active Grignard monomer formation on the end groups and
polydispersity of poly (3-hexylthiophene)(P3HT) for the catalyst transfer polymerization. The …

Impact of copolymer sequence on solid-state properties for random, gradient and block copolymers containing thiophene and selenophene

EF Palermo, AJ McNeil - Macromolecules, 2012 - ACS Publications
Nickel-catalyzed chain-growth copolymerizations of thiophene and selenophene derivatives
afforded well-defined π-conjugated copolymers with narrow molecular weight distributions …

C–H functionalization polycondensation of chlorothiophenes in the presence of nickel catalyst with stoichiometric or catalytically generated magnesium amide

S Tamba, K Shono, A Sugie, A Mori - Journal of the American …, 2011 - ACS Publications
Polymerization of 2-chloro-3-substituted thiophenes proceeded with a stoichiometric amount
of magnesium amide, TMPMgCl· LiCl, or a combination of a Grignard reagent and a catalytic …

Precision Synthesis of Poly (3‐hexylthiophene) from Catalyst‐Transfer Suzuki− Miyaura Coupling Polymerization

T Yokozawa, R Suzuki, M Nojima… - Macromolecular …, 2011 - Wiley Online Library
Abstract tBu3 PPd (Ph) Br (1)‐catalyzed Suzuki‐Miyaura coupling polymerization of 2‐(4‐
hexyl‐5‐iodo‐2‐thienyl)‐4, 4, 5, 5‐tetramethyl‐1, 3, 2‐dioxaborolane (2) was investigated …