A comparison of RAFT and ATRP methods for controlled radical polymerization

NP Truong, GR Jones, KGE Bradford… - Nature Reviews …, 2021 - nature.com
Reversible addition–fragmentation chain-transfer (RAFT) polymerization and atom transfer
radical polymerization (ATRP) are the two most common controlled radical polymerization …

RAFT polymerization to form stimuli-responsive polymers

G Moad - Polymer Chemistry, 2017 - pubs.rsc.org
Stimuli-responsive polymers adapt to their surrounding environment. These polymers are
capable of responding to a variety of external stimuli, which include optical, electrical …

Expanding the scope of RAFT polymerization: recent advances and new horizons

MR Hill, RN Carmean, BS Sumerlin - Macromolecules, 2015 - ACS Publications
Reversible deactivation radical polymerization (RDRP) has revolutionized modern polymer
chemistry over the past two decades, thus laying the groundwork for the synthesis of …

Photoinduced Electron Transfer–Reversible Addition–Fragmentation Chain Transfer (PET-RAFT) Polymerization of Vinyl Acetate and N-Vinylpyrrolidinone: Kinetic …

S Shanmugam, J Xu, C Boyer - Macromolecules, 2014 - ACS Publications
Photoinduced electron transfer–reversible addition–fragmentation chain transfer (PET-
RAFT) polymerization was employed for the polymerization of unconjugated monomers …

Supercritical fluids and polymers–The year in review–2014

E Kiran - The Journal of Supercritical Fluids, 2016 - Elsevier
A critical overview of publications on applications of supercritical fluids in polymer formation,
modification and processing is presented. The review is focused on publications that …

Concurrent control over sequence and dispersity in multiblock copolymers

MN Antonopoulou, R Whitfield, NP Truong, D Wyers… - Nature Chemistry, 2022 - nature.com
Controlling monomer sequence and dispersity in synthetic macromolecules is a major goal
in polymer science as both parameters determine materials' properties and functions …

Cationic RAFT polymerization using ppm concentrations of organic acid

M Uchiyama, K Satoh, M Kamigaito - Angewandte Chemie, 2015 - Wiley Online Library
A metal‐free, cationic, reversible addition–fragmentation chain‐transfer (RAFT)
polymerization was proposed and realized. A series of thiocarbonylthio compounds were …

Ubiquitous Nature of Rate Retardation in Reversible Addition–Fragmentation Chain Transfer Polymerization

KGE Bradford, LM Petit, R Whitfield… - Journal of the …, 2021 - ACS Publications
Reversible addition–fragmentation chain transfer (RAFT) polymerization is one of the most
powerful reversible deactivation radical polymerization (RDRP) processes. Rate retardation …

Poly(N‐vinylcaprolactam): A Thermoresponsive Macromolecule with Promising Future in Biomedical Field

J Liu, A Debuigne, C Detrembleur… - Advanced healthcare …, 2014 - Wiley Online Library
Poly (N‐vinylcaprolactam)(PNVCL) is a thermoresponsive and biocompatible polymer that
raises an increasing interest in the biomedical area, especially in drug delivery systems …

PVA free-radical diblock copolymer for nanoencapsulation with enhanced biodegradability in the environment

SR Mothe, P Kanaujia, ABY Oh, P Ang… - European Polymer …, 2023 - Elsevier
The synthesis of readily biodegradable amphiphilic polyvinyl alcohol diblock copolymers
(poly (VA-b-MDO)) was achieved through the combination of radical ring-opening …