Progress in the self-assembly of organic/inorganic polyhedral oligomeric silsesquioxane (POSS) hybrids

MG Mohamed, SW Kuo - Soft Matter, 2022 - pubs.rsc.org
This Review describes recent progress in the self-assembly of organic/inorganic POSS
hybrids derived from mono-, di-, and multi-functionalized POSS cages. We highlight the self …

Discrete Diblock Copolymers with Tailored Conformational Asymmetry: A Precise Model Platform to Explore Complex Spherical Phases

D Zhou, M Xu, Z Ma, Z Gan, J Zheng, R Tan… - …, 2022 - ACS Publications
Conformational asymmetry of block copolymers is a critical molecular parameter dictating
the self-assembly behaviors. This work develops an efficient approach to construct block …

Discrete giant polymeric chains based on nanosized monomers

Z Liu, Z Yang, X Chen, R Tan, G Li, Z Gan, Y Shao… - Jacs Au, 2020 - ACS Publications
As size-amplified analogues of canonical macromolecules, polymeric chains built up by
“giant” monomers represent an experimental realization of the “beads-on-a-string” model at …

Self-assembly of poly (janus particle) s into unimolecular and oligomeric spherical micelles

Z Li, Z Li, J Hu, X Feng, M Zhang, G Duan… - ACS Macro …, 2021 - ACS Publications
Using shape-persistent Janus particles to construct poly (Janus particle) s and studying their
self-assembly behaviors are of great interest, but remain largely unexplored. In this work, we …

Unique Viscoelasticity and Hierarchical Relaxation Dynamics of Molecular Granular Materials

W Liu-Fu, H Xiao, J Chen, L Cai, J Yang, B Xue… - Nano Letters, 2024 - ACS Publications
Resulting from the dense packing of subnanometer molecular clusters, molecular granular
materials (MGMs) are shown to maintain high elasticity far above their apparent glass …

Precise amphiphilic giant polymeric chain based on nanosized monomers with exact regio-configuration

Z Liu, X Chen, Z Yang, S Wang, Z Gan, G Li, XH Dong - ACS nano, 2021 - ACS Publications
Polymeric chains made of “giant” monomers at a larger length scale provide intriguing
insights into the fundamental principles of polymer science. In this study, we modularly …

Discrete giant polymeric chain with precise sequence and regio-configuration: a concise multiblock model system

Z Liu, S Wang, G Li, Z Yang, Z Gan, XH Dong - Macromolecules, 2022 - ACS Publications
The vastly expanding chemical and architectural parameter space of multiblock copolymers
brings both opportunities and challenges for tailoring the structure and properties of a …

Thickness control of 2D nanosheets assembled from precise side-chain giant molecules

F Feng, D Guo, Y Shao, X Yan, K Yue, Z Pan, X Li… - Chemical …, 2021 - pubs.rsc.org
The performance of 2D nanomaterials hinges on both the chemical compositions and the
morphological structures across different length scales. Among all the three dimensions …

Diameter and elasticity governing the relaxation of soft-nanoparticle melts

J Luo, Y Zhu, Y Ruan, W Wu, X Ouyang, Z Du… - …, 2021 - ACS Publications
Acting as soft-nanoparticles, series of microgels are microemulsion polymerized and
investigated for their dynamics in the melt state. Each series is kept at the same average …

[HTML][HTML] Coarse-grained soft-clusters remain non-diffusing in the melt state

Q Zou, Y Zhu, Y Ruan, R Zhang, GX Liu - Giant, 2021 - Elsevier
Melts of 3-dimensional dendritic beads-springs, namely coarse-grained soft-clusters, are
studied by molecular dynamics simulations. The goal is to elucidate the unique dynamics of …