In the past decades, the iridium-catalyzed C–H bond borylation and other newly discovered
catalytic borylation reactions have received extensive research interests and developed into …

At the advent of cross-coupling chemistry, carbon electrophiles based on halides or
pseudohalides were the only suitable electrophilic coupling partners. Almost two decades …

Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …

1, 2-Disubstituted alkenes such as vinyl arenes, vinyl silanes, and vinyl boronates are
among the most versatile building blocks that can be found in every sector of chemical …

We report herein a new method for the photoredox activation of boronic esters. Using these
reagents, an efficient and high‐throughput continuous flow process was developed to …

Herein, we report a regioselective alkenyl electrophile synthesis from unactivated olefins
that is based on a direct and regioselective C− H thianthrenation reaction. The selectivity is …

This Review examines parts per million (ppm) palladium concentrations in catalytic cross-
coupling reactions and their relationship with mole percentage (mol%). Most studies in …

The palladium-catalyzed oxidative borylation reaction of N-tosylhydrazones has been
developed. The reaction features mild conditions, broad substrate scope, and good …

An unprecedented arylboration of unactivated terminal alkenes, featuring 1, n‐
regioselectivity, has been achieved by nickel catalysis. The nitrogen‐based ligand plays an …

Stereochemically defined tetrasubstituted olefins are widespread structural elements of
organic molecules and key intermediates in organic synthesis. However, flexible methods …