Designing artificial metalloenzymes by tuning of the environment beyond the primary coordination sphere
Metalloenzymes catalyze a variety of reactions using a limited number of natural amino
acids and metallocofactors. Therefore, the environment beyond the primary coordination …
acids and metallocofactors. Therefore, the environment beyond the primary coordination …
Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …
reactions are widely performed during single and multistep synthesis. However, besides the …
The Hitchhiker's guide to biocatalysis: recent advances in the use of enzymes in organic synthesis
Enzymes are excellent catalysts that are increasingly being used in industry and academia.
This perspective is primarily aimed at synthetic organic chemists with limited experience …
This perspective is primarily aimed at synthetic organic chemists with limited experience …
Highly Robust Iron Catalyst System for Intramolecular C(sp3)−H Amidation Leading to γ‐Lactams
Disclosed here is the use of an iron catalyst system for an intramolecular C− H amidation
toward γ‐lactam synthesis from dioxazolone precursors.(Phthalocyanine) FeIIICl was found …
toward γ‐lactam synthesis from dioxazolone precursors.(Phthalocyanine) FeIIICl was found …
Unravelling nitrene chemistry from acyclic precursors: recent advances and challenges
YC Wang, XJ Lai, K Huang, S Yadav, G Qiu… - Organic Chemistry …, 2021 - pubs.rsc.org
Recent advances in nitrene chemistry from acyclic precursors are reviewed in this paper.
Early developments in nitrene chemistry predominantly focused on exploiting new nitrene …
Early developments in nitrene chemistry predominantly focused on exploiting new nitrene …
Modification of pulse proteins for improved functionality and flavor profile: A comprehensive review
Consumers' preference to have a healthy eating pattern has led to an increasing demand for
more nutrient‐dense and healthier plant‐based foods. Pulse proteins are exceptional quality …
more nutrient‐dense and healthier plant‐based foods. Pulse proteins are exceptional quality …
Ionic liquids for regulating biocatalytic process: Achievements and perspectives
P Xu, S Liang, MH Zong, WY Lou - Biotechnology advances, 2021 - Elsevier
Biocatalysis has found enormous applications in sorts of fields as an alternative to chemical
catalysis. In the pursue of green and sustainable chemistry, ionic liquids (ILs) have been …
catalysis. In the pursue of green and sustainable chemistry, ionic liquids (ILs) have been …
Expanding the structural diversity of terpenes by synthetic biology approaches
R Chen, M Wang, JD Keasling, T Hu, X Yin - Trends in Biotechnology, 2024 - cell.com
Terpenoids display chemical and structural diversities as well as important biological
activities. Despite their extreme variability, the range of these structures is limited by the …
activities. Despite their extreme variability, the range of these structures is limited by the …
Iron: A worthy contender in metal carbene chemistry
VF Batista, DC GA Pinto, AMS Silva - ACS Catalysis, 2020 - ACS Publications
Carbene transfer reactions hold a pivotal role in organic synthesis, allowing the prompt
construction of complex molecules from accessible reagents. Iron complexes emerged as …
construction of complex molecules from accessible reagents. Iron complexes emerged as …
Highly Regioselective Cyclodehydrogenation of Diphenylporphyrin on Metal Surfaces
Y Zhang, J Lu, H Zhou, G Zhang, Z Ruan, Y Zhang… - ACS …, 2023 - ACS Publications
Exploring the effect of porphin tautomerism on the regioselectivity of its derivatives is a big
challenge, which is significant for the development and application of porphyrin drugs. In this …
challenge, which is significant for the development and application of porphyrin drugs. In this …