The present Minireview highlights the most representative and emerging developments
reported since 2012 on the use of well‐defined group 13 metal species in homogeneous …

Herein, we report an efficient one-pot iridium-catalyzed reductive hydroamination of terminal
alkynes with amines. A variety of primary amines and secondary amines are amenable to …

This review highlights the recent achievements in replacing precious-metal-based catalysts
with nonprecious-metal-based catalysts in two important syntheses: hydroamination and C …

We report a Chan–Lam coupling reaction of benzylic and allylic boronic esters with primary
and secondary anilines to form valuable alkyl amine products. Both secondary and tertiary …

A novel synthesis of α-aminonitriles is described via an indium-catalyzed three-component
coupling reaction of alkynes, amines, and trimethylsilyl cyanide (Me3SiCN). Hydroamination …

A metal-free one-pot synthesis of secondary amines from aryl alkynes via hydration-
condensation-reduction three-step process in the presence of TfOH and B 2 (OH) 4 has …

Abstract Digallane (dpp-bian) Ga—Ga (dpp-bian)(1)(dpp-bian is the 1, 2-bis [(2, 6-
diisopropylphenyl) imino] acenaphthene) catalyzes the addition of 4-chloroaniline to some …

An efficient method for the N‐alkylation of poorly nucleophilic amines using ferric
perchlorate immobilized on SiO2 as a catalyst is described. Fe (ClO4) 3 was prepared from …

A new imidazo [1, 5-a] pyridine-containing pyrrolyl ligand HL (HL= 3-(1H-pyrrol-2-yl) imidazo
[1, 5-a] pyridine) was synthesized and employed in the organometallic chemistry of titanium …

摘要近年来有关受限路易斯酸碱对(FLPs) 化学的研究受到了国内外的广泛关注,
但有关芳香胺类FLPs 的应用研究却极少涉及. 本工作以硅烷作为还原剂, 路易斯酸三(五氟苯基) …