Recent advances in heterocyclic nanographenes and other polycyclic heteroaromatic compounds

A Borissov, YK Maurya, L Moshniaha… - Chemical …, 2021 - ACS Publications
This review surveys recent progress in the chemistry of polycyclic heteroaromatic molecules
with a focus on structural diversity and synthetic methodology. The article covers literature …

Fluorescent cyclophanes and their applications

I Roy, AHG David, PJ Das, JP David… - Chemical Society …, 2022 - pubs.rsc.org
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …

Recognition and applications of anion–anion dimers based on anti-electrostatic hydrogen bonds (AEHBs)

W Zhao, AH Flood, NG White - Chemical Society Reviews, 2020 - pubs.rsc.org
Based on Coulomb's Law alone, electrostatic repulsion between two anions is expected to
prevent their dimerization. Contrary to that idea, this Tutorial Review will present evidence …

Tunable adhesion from stoichiometry-controlled and sequence-defined supramolecular polymers emerges hierarchically from cyanostar-stabilized anion–anion …

W Zhao, J Tropp, B Qiao, M Pink… - Journal of the …, 2020 - ACS Publications
Sequence-controlled supramolecular polymers offer new design paradigms for generating
stimuli-responsive macromolecules with enhanced functionalities. The dynamic character of …

Allosteric control of photofoldamers for selecting between anion regulation and double-to-single helix switching

FC Parks, Y Liu, S Debnath, SR Stutsman… - Journal of the …, 2018 - ACS Publications
Allosteric regulation of protein structure and function is a hallmark of biology. The structures
of protein-like abiological foldamers have been subject to allosteric control, however …

Recognition-guided sulfate extraction and transport using tripodal hexaurea receptors

SQ Chen, SN Yu, W Zhao, L Liang, Y Gong… - Inorganic Chemistry …, 2022 - pubs.rsc.org
The separation of sulfate anions (SO42−) from water is a great challenge due to its high
hydration energy. Using synthetic receptors that are designed with a size-complementary …

“Anti‐electrostatic” Halogen Bonding between Ions of Like Charge

JM Holthoff, R Weiss, SV Rosokha… - Chemistry–A European …, 2021 - Wiley Online Library
Halogen bonding occurs between molecules featuring Lewis acidic halogen substituents
and Lewis bases. It is often rationalized as a predominantly electrostatic interaction and thus …

Linear supramolecular polymers driven by anion–anion dimerization of difunctional phosphonate monomers inside cyanostar macrocycles

W Zhao, B Qiao, J Tropp, M Pink… - Journal of the …, 2019 - ACS Publications
Supramolecular polymers have enabled far-reaching fundamental science and the
development of diverse macromolecular technologies owing to the reversible and …

Zero-overlap fluorophores for fluorescent studies at any concentration

A Dhara, T Sadhukhan, EG Sheetz… - Journal of the …, 2020 - ACS Publications
Fluorophores are powerful tools for the study of chemistry, biology, and physics. However,
fluorescence is severely impaired when concentrations climb above 5 μM as a result of …

Interfacial supramolecular structures of amphiphilic receptors drive aqueous phosphate recognition

JF Neal, W Zhao, AJ Grooms, MA Smeltzer… - Journal of the …, 2019 - ACS Publications
Phosphate remediation is important for preventing eutrophication in fresh waters and
maintaining water quality. One approach for phosphate removal involves the utilization of …