Merging hydrogen (H2) evolution with oxidative organic synthesis in a semiconductor-
mediated photoredox reaction is extremely attractive because the clean H2 fuel and high …

Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Conspectus Electrochemical organic oxidation reactions are highly appealing because
protons are often effective terminal electron acceptors, thereby avoiding undesirable …

N-Oxyl compounds represent a diverse group of reagents that find widespread use as
catalysts for the selective oxidation of organic molecules in both laboratory and industrial …

The oxygen reduction reaction (ORR) is a key component of biological processes and
energy technologies. This Review provides a comprehensive report of soluble molecular …

Lignocellulose, the main component of agricultural and forestry waste, harbours tremendous
potential as a renewable starting material for future biorefinery practices. However, this …

The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …

Copper is one of the most abundant and less toxic transition metals. Nature takes advantage
of the bioavailability and rich redox chemistry of Cu to carry out oxygenase and oxidase …

Conspectus Selective oxidation reactions have extraordinary value in organic chemistry,
ranging from the conversion of petrochemical feedstocks into industrial chemicals and …

Oxidations of alcohols and amines are common reactions in the synthesis of organic
molecules in the laboratory and industry. Aerobic oxidation methods have long been sought …