Advanced development strategy of nano catalyst and DFT calculations for direct synthesis of hydrogen peroxide
Hydrogen peroxide is a simple oxidizing agent. Its environmental benignness and
effectiveness have led to a continuous increase in its use and production. Anthraquinone …
effectiveness have led to a continuous increase in its use and production. Anthraquinone …
Looking for the “dream catalyst” for hydrogen peroxide production from hydrogen and oxygen
The reaction between hydrogen and oxygen is in principle the simplest method to form
hydrogen peroxide, but it is still a “dream process”, thus needing a “dream catalyst”. The aim …
hydrogen peroxide, but it is still a “dream process”, thus needing a “dream catalyst”. The aim …
Trace Pt atoms as electronic promoters in Pd clusters for direct synthesis of hydrogen peroxide
Y Zhang, Q Sun, G Guo, Y Cheng, X Zhang, H Ji… - Chemical Engineering …, 2023 - Elsevier
Abstract Hydrogen peroxide (H 2 O 2), one of the most versatile oxidants in industry, is
widely used in the production of chemicals and medicines, sterilization, and bleaching. The …
widely used in the production of chemicals and medicines, sterilization, and bleaching. The …
Efficient Direct H2O2 Synthesis Enabled by PdPb Nanorings via Inhibiting the O–O Bond Cleavage in O2 and H2O2
Direct H2O2 synthesis (DHS) from H2 and O2 is a promising process in industry; however,
challenges related to poor H2O2 selectivity and low H2O2 yield remain. We report here that …
challenges related to poor H2O2 selectivity and low H2O2 yield remain. We report here that …
Microkinetic Modeling with Size-Dependent and Adsorbate–Adsorbate Interactions for the Direct Synthesis of H2O2 over Pd Nanoparticles
As a bottleneck in the direct synthesis of hydrogen peroxide, the development of an efficient
palladium-based catalyst has garnered great attention. However, elusive active centers and …
palladium-based catalyst has garnered great attention. However, elusive active centers and …
Cyclohexanone ammoximation via in situ H 2 O 2 production using TS-1 supported catalysts
The ammoximation of cyclohexanone to the corresponding oxime via in situ H2O2 formation
offers an attractive alternative to the current industrial means of production, overcoming the …
offers an attractive alternative to the current industrial means of production, overcoming the …
Active oxygen species promoted catalytic oxidation of 5-hydroxymethyl-2-furfural on facet-specific Pt nanocrystals
The aerobic oxidation of alcohols and aldehydes over noble metal catalysts is a critical
reaction for the catalytic conversion of carbohydrates into value-added chemicals from …
reaction for the catalytic conversion of carbohydrates into value-added chemicals from …
Self-assembled synthesis of Pd/SPEn from polyelectrolyte membranes for efficient direct synthesis of H2O2 via inhibiting the dissociation of O− O bond
E Ye, Z Chen, Y Shi, D Zhang, W Li, H Qin, Z Luo… - Chemical Engineering …, 2023 - Elsevier
Although a high-activity yield of hydrogen peroxide (H 2 O 2) can be achieved by direct
synthesis from hydrogen and oxygen, developing an extreme catalyst with high activity and …
synthesis from hydrogen and oxygen, developing an extreme catalyst with high activity and …
Quantitative Insights into the Reaction Mechanism for the Direct Synthesis of H2O2 over Transition Metals: Coverage-Dependent Microkinetic Modeling
The direct synthesis is the most promising alternative method for the production of hydrogen
peroxide, and the bottleneck is still unsolved. The breakthrough lies in elusive reaction …
peroxide, and the bottleneck is still unsolved. The breakthrough lies in elusive reaction …
Enhancing catalytic performance of AuPd catalysts towards the direct synthesis of H 2 O 2 through incorporation of base metals
The introduction of small quantities of tertiary base metals into supported AuPd
nanoparticles results in improved catalytic performance towards the direct synthesis of …
nanoparticles results in improved catalytic performance towards the direct synthesis of …