Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

CO2 Capture and Separations Using MOFs: Computational and Experimental Studies

J Yu, LH Xie, JR Li, Y Ma, JM Seminario… - Chemical …, 2017 - ACS Publications
This Review focuses on research oriented toward elucidation of the various aspects that
determine adsorption of CO2 in metal–organic frameworks and its separation from gas …

Catalytic zirconium/hafnium-based metal–organic frameworks

M Rimoldi, AJ Howarth, MR DeStefano, L Lin… - Acs …, 2017 - ACS Publications
Metal–organic frameworks (MOFs) are highly versatile materials that find applications in
several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and …

A promising metal–organic framework (MOF), MIL-96 (Al), for CO 2 separation under humid conditions

V Benoit, N Chanut, RS Pillai, M Benzaqui… - Journal of Materials …, 2018 - pubs.rsc.org
The CO2 adsorption uptake and enthalpies with MIL-96 (Al) were assessed in the presence
of up to 40% relative humidity via both experiment and simulation. Interestingly at 10 …

Cooperative CO 2 adsorption mechanism in a perfluorinated Ce IV-based metal organic framework

M Cavallo, C Atzori, M Signorile, F Costantino… - Journal of Materials …, 2023 - pubs.rsc.org
Adsorbents able to uptake large amounts of gases within a narrow range of pressure, ie,
phase-change adsorbents, are emerging as highly interesting systems to achieve excellent …

The roles of metal-organic frameworks in modulating water permeability of graphene oxide-based carbon membranes

X Sui, H Ding, Z Yuan, CF Leong, K Goh, W Li, N Yang… - Carbon, 2019 - Elsevier
Graphene oxide (GO) can be processed into carbon membranes with unique water
permeability and molecular selectivity. Metal-organic frameworks (MOFs) have been …

Comparative analysis of calculation method of adsorption isosteric heat: Case study of CO2 capture using MOFs

Z Du, X Nie, S Deng, L Zhao, S Li, Y Zhang… - … and Mesoporous Materials, 2020 - Elsevier
The isosteric heat of adsorption (q st) is a critical parameter to describe the CO 2 adsorption
separation system for the determination of energy consumption of regeneration. The q st …

Enhanced acidity of defective MOF-808: effects of the activation process and missing linker defects

C Ardila-Suárez, S Perez-Beltran… - Catalysis Science & …, 2018 - pubs.rsc.org
Among the zirconium-based metal–organic frameworks, MOF-808 has been reported as a
promising heterogeneous catalyst due to its inherent missing linker defects. In this work, we …

Hydrogen evolution from NaBH4 using novel Ni/Pt nanoparticles decorated on a niobium-based composite

GH Sperandio, JP de Carvalho, CBR de Jesus… - International Journal of …, 2024 - Elsevier
The niobium-based nanocomposite (Nb-CP), inspired by MOF-based synthesis, was
developed utilizing the ligands 4-benzenedicarboxylic acid (BDC) and 1, 3, 5 …

Recent advances of computational simulations on carbon capture in MOFs

Q Shuai, WL Li, C Zhao, J Yu - Materials Today Communications, 2024 - Elsevier
Carbon dioxide emissions have become a pressing global issue, commanding widespread
attention. Metal-organic frameworks (MOFs) are recognized as one of the most promising …