Photo‐response with radical afterglow by regulation of spin populations and hole‐electron distributions

Y Yang, J Wang, J Yang, L Tong, D Li… - Angewandte Chemie …, 2023 - Wiley Online Library
No matter photoinduced organic radicals have been reported frequently, they are usually
non‐luminescent at ambient conditions. The internal mechanism on stability and electronic …

Isoreticular Contraction of Metal–Organic Frameworks Induced by Cleavage of Covalent Bonds

Y Yang, P Fernández-Seriñán, I Imaz… - Journal of the …, 2023 - ACS Publications
Isoreticular chemistry, in which the organic or inorganic moieties of reticular materials can be
replaced without destroying their underlying nets, is a key concept for synthesizing new …

π-Stacks of radical-anionic naphthalenediimides in a metal-organic framework

B Kim, J Lee, YP Chen, XQ Wu, J Kang, H Jeong… - Science …, 2022 - science.org
Radical-ionic metal-organic frameworks (MOFs) have unique optical, magnetic, and
electronic properties. These radical ions, forcibly formed by external stimulus-induced redox …

Tuning redox activity in metal–organic frameworks: From structure to application

SAA Razavi, W Chen, HC Zhou, A Morsali - Coordination Chemistry …, 2024 - Elsevier
Among the various characteristics of metal–organic frameworks (MOFs), redox activity, the
ability to store or release electrons is a vital property for functional MOFs in applications like …

Titanium-based metal-organic frameworks as pH-responsive drug delivery carriers of 5-Fluorouracil

J Chen, C Wang, ZY Zhu, F Wang, J Shang… - Journal of Solid State …, 2024 - Elsevier
In this study, we synthesized two titanium-based metal-organic frameworks (Ti-MOFs),
namely MIL-125 and MIL-125-NH 2, known for their excellent biocompatibility, as potential …

Photoelectromagnetic Responsive Adaptive Porous Frameworks through Dynamic Covalent Chemistry of Tetraarylethylene‐backboned Aryldicyanomethyl Radicals

X Wang, H Zhang, H Liu, G Xu, W Lai… - Angewandte Chemie …, 2023 - Wiley Online Library
Dynamic materials undergoing adaptive solid‐state transitions are attractive for soft
mechanics and information technology. Here, we report a novel porous framework system …

Up–down approach for expanding the chemical space of metal–organic frameworks

J Kim, D Nam, HJ Cho, E Cho, D Sivanesan, C Cho… - Nature …, 2024 - nature.com
The vast structural diversity of metal–organic frameworks (MOFs) and the ability to tailor the
structures makes the materials applicable for a broad range of uses. Traditional bottom-up …

Photoexcited Single-Electron Transfer for Efficient Green Synthesis of Cyclic Carbonate from CO2

L Li, W Liu, T Shi, S Shang, X Zhang, H Wang… - ACS Materials …, 2023 - ACS Publications
It is attractive but challenging to produce high-value-added cyclic carbonates at ambient
condition by the 100% atom-economic photocatalytic cycloaddition of CO2, which is limited …

Confinement‐Driven Photophysics in Hydrazone‐Based Hierarchical Materials

GC Thaggard, GA Leith, D Sosnin… - Angewandte Chemie …, 2023 - Wiley Online Library
Confinement‐imposed photophysics was probed for novel stimuli‐responsive hydrazone‐
based compounds demonstrating a conceptual difference in their behavior within 2D versus …

Metal–Organic Framework with Structural Flexibility Responding Specifically to Acetylene and Its Adsorption Behavior

HZ Li, QH Li, M Yao, YP Han, K Otake… - … Applied Materials & …, 2022 - ACS Publications
Flexible metal–organic frameworks (MOFs) are one kind of stimuli-responsive materials that
exhibit reversible structural transformations in response to external stimuli. Exploring and …