Polyelectrolyte brushes: theory, modelling, synthesis and applications

S Das, M Banik, G Chen, S Sinha, R Mukherjee - Soft Matter, 2015 - pubs.rsc.org
Polyelectrolyte (PE) brushes are a special class of polymer brushes (PBs) containing
charges. Polymer chains attain “brush”-like configuration when they are grafted or get …

Colloquium: Phase transitions in polymers and liquids in electric fields

Y Tsori - Reviews of Modern Physics, 2009 - APS
The structure and thermodynamic state of a system changes under the influence of external
electric fields. Neutral systems are characterized by their dielectric constant ε, while charged …

Electroosmotic transport in polyelectrolyte-grafted nanochannels with pH-dependent charge density

G Chen, S Das - Journal of Applied Physics, 2015 - pubs.aip.org
“Smart” polyelectrolyte-grafted or “soft” nanochannels with pH-responsiveness have shown
great promise for applications like manipulation of ion transport, ion sensing and selection …

Massively enhanced electroosmotic transport in nanochannels grafted with end-charged polyelectrolyte brushes

G Chen, S Das - The Journal of Physical Chemistry B, 2017 - ACS Publications
We establish that nanochannels grafted with pH-responsive, end-charged polyelectrolyte
(PE) brushes demonstrate a massive augmentation in the strength of the electroosmotic …

Efficient electrochemomechanical energy conversion in nanochannels grafted with end-charged polyelectrolyte brushes at medium and high salt concentration

G Chen, HS Sachar, S Das - Soft Matter, 2018 - pubs.rsc.org
We develop a theory to study the generation of the streaming potential and the resulting
electrochemomechanical energy conversion (ECMEC) in the presence of pressure-driven …

Water soluble responsive polymer brushes

MP Weir, AJ Parnell - Polymers, 2011 - mdpi.com
Responsive polymer brushes possess many interesting properties that enable them to
control a range of important interfacial behaviours, including adhesion, wettability, surface …

Polyelectrolyte brushes in external fields: molecular dynamics simulations and mean-field theory

H Merlitz, C Li, C Wu, JU Sommer - Soft Matter, 2015 - pubs.rsc.org
A mean-field model is developed to predict the layer-thickness of sparse and salt-free
polyelectrolyte brushes, exposed to an external electric field, which attracts the …

Ionic diffusoosmosis in nanochannels grafted with end-charged polyelectrolyte brushes

RS Maheedhara, HS Sachar, H Jing… - The Journal of Physical …, 2018 - ACS Publications
In this paper, we develop a theory to study the imposed axial salt-concentration-gradient-
driven ionic diffusioosmosis (IDO) in soft nanochannels or nanochannels grafted with end …

Anomalous shrinking–swelling of nanoconfined end-charged polyelectrolyte brushes: Interplay of confinement and electrostatic effects

G Chen, S Das - The Journal of Physical Chemistry B, 2016 - ACS Publications
In this article, we model the structure and configuration of the end-charged polyelectrolyte
(PE) brushes grafted on the inner walls of a nanochannel. When the confinement effect is …

Effect of finite ion sizes in electric double layer mediated interaction force between two soft charged plates

J Andrews, S Das - RSC Advances, 2015 - pubs.rsc.org
We present a theory to compute the electric-double-layer (EDL) mediated per unit area
interaction force, or the osmotic pressure, between two soft charged plates separated by a …