Polyelectrolyte brushes: theory, modelling, synthesis and applications
Polyelectrolyte (PE) brushes are a special class of polymer brushes (PBs) containing
charges. Polymer chains attain “brush”-like configuration when they are grafted or get …
charges. Polymer chains attain “brush”-like configuration when they are grafted or get …
Colloquium: Phase transitions in polymers and liquids in electric fields
Y Tsori - Reviews of Modern Physics, 2009 - APS
The structure and thermodynamic state of a system changes under the influence of external
electric fields. Neutral systems are characterized by their dielectric constant ε, while charged …
electric fields. Neutral systems are characterized by their dielectric constant ε, while charged …
Electroosmotic transport in polyelectrolyte-grafted nanochannels with pH-dependent charge density
“Smart” polyelectrolyte-grafted or “soft” nanochannels with pH-responsiveness have shown
great promise for applications like manipulation of ion transport, ion sensing and selection …
great promise for applications like manipulation of ion transport, ion sensing and selection …
Massively enhanced electroosmotic transport in nanochannels grafted with end-charged polyelectrolyte brushes
We establish that nanochannels grafted with pH-responsive, end-charged polyelectrolyte
(PE) brushes demonstrate a massive augmentation in the strength of the electroosmotic …
(PE) brushes demonstrate a massive augmentation in the strength of the electroosmotic …
Efficient electrochemomechanical energy conversion in nanochannels grafted with end-charged polyelectrolyte brushes at medium and high salt concentration
We develop a theory to study the generation of the streaming potential and the resulting
electrochemomechanical energy conversion (ECMEC) in the presence of pressure-driven …
electrochemomechanical energy conversion (ECMEC) in the presence of pressure-driven …
Water soluble responsive polymer brushes
MP Weir, AJ Parnell - Polymers, 2011 - mdpi.com
Responsive polymer brushes possess many interesting properties that enable them to
control a range of important interfacial behaviours, including adhesion, wettability, surface …
control a range of important interfacial behaviours, including adhesion, wettability, surface …
Polyelectrolyte brushes in external fields: molecular dynamics simulations and mean-field theory
H Merlitz, C Li, C Wu, JU Sommer - Soft Matter, 2015 - pubs.rsc.org
A mean-field model is developed to predict the layer-thickness of sparse and salt-free
polyelectrolyte brushes, exposed to an external electric field, which attracts the …
polyelectrolyte brushes, exposed to an external electric field, which attracts the …
Ionic diffusoosmosis in nanochannels grafted with end-charged polyelectrolyte brushes
In this paper, we develop a theory to study the imposed axial salt-concentration-gradient-
driven ionic diffusioosmosis (IDO) in soft nanochannels or nanochannels grafted with end …
driven ionic diffusioosmosis (IDO) in soft nanochannels or nanochannels grafted with end …
Anomalous shrinking–swelling of nanoconfined end-charged polyelectrolyte brushes: Interplay of confinement and electrostatic effects
In this article, we model the structure and configuration of the end-charged polyelectrolyte
(PE) brushes grafted on the inner walls of a nanochannel. When the confinement effect is …
(PE) brushes grafted on the inner walls of a nanochannel. When the confinement effect is …
Effect of finite ion sizes in electric double layer mediated interaction force between two soft charged plates
J Andrews, S Das - RSC Advances, 2015 - pubs.rsc.org
We present a theory to compute the electric-double-layer (EDL) mediated per unit area
interaction force, or the osmotic pressure, between two soft charged plates separated by a …
interaction force, or the osmotic pressure, between two soft charged plates separated by a …