Tetrylenes based on tri-and tetradentate ONO-, NNO-, NNN-, and ONNO-type ligands: synthesis, structure, and reactivity

SS Karlov, GS Zaitseva, MP Egorov - Russian Chemical Bulletin, 2019 - Springer
The review discusses the results of the authors' research aimed at the synthesis of stable
tetrylenes (germylenes and stannylenes) and the determination of the structure of these …

Palladium complexes with stabilized germylene and stannylene ligands

MM Kireenko, KV Zaitsev, YF Oprunenko… - Dalton …, 2013 - pubs.rsc.org
The syntheses of novel Pd complexes with germylene and stannylene ligands are
reported.[MeN (CH2CH2NC6F5) 2Sn] 4Pd (2) and [MeN (CH2CPh2O)(CH2CH2O) Ge] 4Pd …

Extending the family of stable heavier carbenes: New tetrylenes based on N, N, O-ligands

KV Zaitsev, VS Cherepakhin, AV Churakov… - Inorganica Chimica …, 2016 - Elsevier
A series of novel heavier carbene analogs 3–8, MeN (CH 2 CH 2 NTs)(CH 2 CR 2 O) M (M=
Ge (3, R= H; 4, R= Ph), Sn (5, R= H; 6, R= Ph), Pb (7, R= H; 8, R= Ph)), was prepared by the …

Germanium Complexes with ONO Tridentate Ligands: OH Bond Activation Control According to DFT Calculations

KV Zaitsev, AD Trubachev, OK Poleshchuk - International Journal of …, 2023 - mdpi.com
Polydentate ligands are used for thermodynamic stabilization of tetrylenes—low-valent
derivatives of Group 14 elements (E= Si, Ge, Sn, Pb). This work shows by DFT calculations …

Aluminum complexes based on pyridine substituted alcohols: synthesis, structure, and catalytic application in ROP

MM Kireenko, EA Kuchuk, KV Zaitsev… - Dalton …, 2015 - pubs.rsc.org
A series of substituted pyridine dialcohols (2, 6-bis (hydroxyalkyl) pyridines), 1–4, was used
for the synthesis of various types of aluminum complexes. Aluminum methyl derivatives, 2 …

Synthesis and structural characterization of low-valent group 14 metal complexes based on aminobisphenol ligands

KV Zaitsev, EA Kuchuk, AV Churakov… - Inorganica Chimica …, 2017 - Elsevier
Abstract Aminobisphenol supported germylenes (1a–3a), stannylenes (1b–3b) and
plumbylenes (1c–3c) were synthesized by reaction of Lappert's tetrylenes,[(Me 3 Si) 2 N] 2 M …

Stabilized germylenes based on diethylenetriamines and related diamines: Synthesis, structures, and chemical properties

M Huang, MM Kireenko, KV Zaitsev… - European Journal of …, 2012 - Wiley Online Library
A series of novel, low‐valent germanium compounds 2a–2j based on four
diethylenetriamines 1a–1d,(methyl) bis (pyrrol‐2‐ylmethyl) amine (1e), N, N …

Synthesis of ONO‐Ligated Tetrylenes Based on 2, 6‐bis (2‐Hydroxyphenyl) pyridines: Influence of Ligand Sterics on the Structure of the Products

BN Mankaev, VA Serova… - European Journal of …, 2023 - Wiley Online Library
A series of novel tetrylenes based on three 2, 6‐bis (2‐hydroxyphenyl) pyridines 4 a–4 c
have been obtained by the reaction of Lappert's tetrylenes E [N (SiMe3) 2] 2 (E= Ge, Sn) with …

Sterically hindered tetrylenes based on new 1, 10-phenanthroline-containing diols: Initiators for ε-caprolactone polymerization

BN Mankaev, KV Zaitsev, GS Zaitseva… - Russian Chemical …, 2019 - Springer
Previously unknown tetradentate ONNO-type ligands 1–5 (4, 7-di (4-R´-phenoxy)-2, 9-di
(HOCR 2 CH)-1, 10-phenanthrolines (R´= Me, R–R=–(CH 2) 5–(1), R= Me (2), R–R= 2, 2 …

Tetrylenes based on 1, 10-phenanthroline-containing diol: the synthesis and application as initiators of ε-caprolactone polymerization

BN Mankaev, KV Zaitsev, VS Timashova… - Russian Chemical …, 2018 - Springer
Abstract Treatment of 4, 7-dichloro-2, 9-dimethyl-1, 10-phenanthroline with two equivalents
of p-tert-butylphenol in the presence of К 2 СО 3 afforded 4, 7-di (4-tert-butylphenoxy)-2, 9 …