A new type of cage inherent chirality was accessed by hierarchical desymmetrization of a D
3 h-symmetric prismlike cage motif. The dissymmetric C 3 v cage precursor C1 bearing two …

Deep cavitands, concave molecular containers, represent an important supramolecular host
class that has been explored for a variety of applications ranging from sensing, switching …

The stereoselective formation of tetrasubstituted alkenes remains one of the key goals of
modern organic synthesis. In addition to other methods, the stereoselective synthesis of …

Molecules with nonplanar architectures are highly desirable due to their unique topological
structures and functions. We report here the synthesis of two molecular containers (1⋅ 3Br …

Cavitands have emerged as privileged architectures in supramolecular chemistry.
Nonetheless, achieving structural diversity and tunability through heterofunctionalization …

In this study, we describe a synthetic method for incorporating arenes into closed tubes that
we name capsularenes. First, we prepared vase‐shaped molecular baskets 4–7. The …

Abstract Tiefe Kavitanden, konkave molekulare Behälter, stellen eine wichtige
supramolekulare Wirtsklasse dar, die für eine Vielzahl von Anwendungen erforscht wurde …

We report Pd‐catalyzed cyclotrimerization of (+)‐α‐bromoenone, obtained from
monoterpene β‐pinene, into an enantiopure cyclotrimer. This C3 symmetric compound has …

Dans une première partie, les travaux de cette thèse portent sur la synthèse des
cryptophanes et leurs applications potentielles. Ces composés constitués de deux unités …

Significance: Asymmetric cavities exist widely in proteins for selective binding to different
substrates. In contrast, abiotic hosts are usually symmetric because they are much easier to …