Arynes are among the most active organic intermediates and have found numerous
applications in expeditious preparation of substituted arenes. In the past 20 years, chemists …

This Feature Article is aimed at highlighting the recent developments in the transition-metal-
free molecular rearrangements involving arynes. The chemistry of arynes has shown …

The distortion/interaction model has been used to explain and predict reactivity in a variety
of reactions where more common explanations, such as steric and electronic factors, do not …

The synthesis of four novel crystalline zeolitic imidazolate framework (ZIF) structures using a
mixed-ligand approach is reported. The inclusion of both imidazolate and halogenated …

Arynes are neutral intermediates in which two adjacent atoms of an aromatic ring lack
substituents, thus leaving two atomic orbitals (perpendicular to the aromatic x system) to …

An efficient, transition-metal-free procedure for the N-arylation of amines, sulfonamides, and
carbamates and O-arylation of phenols and carboxylic acids has been achieved by allowing …

In the field of modern organic chemistry, hypervalent compounds have become
indispensable tools for synthetic chemists, finding widespread applications in both academic …

Benzyne Click Chemistry: Synthesis of Benzotriazoles from Benzynes and Azides | Organic
Letters ACS ACS Publications C&EN CAS Find my institution Log In Organic Letters ACS …

Despite the widespread application of hypervalent iodines, the corresponding λ3‐bromanes
are less explored. Herein we report a general, safe, and high‐yielding strategy to access …

A wide variety of 3-halospiro [4.5] trienones are readily prepared in good to excellent yields
by the intramolecular ipso-halocyclization of 4-(p-methoxyaryl)-1-alkynes under mild …