Novel process windows for enabling, accelerating, and uplifting flow chemistry
Abstract Novel Process Windows make use of process conditions that are far from
conventional practices. This involves the use of high temperatures, high pressures, high …
conventional practices. This involves the use of high temperatures, high pressures, high …
Flow approaches towards sustainability
Green chemistry and flow chemistry are ideal partners for accessing novel chemical spaces
and define highly efficient synthetic tools. In this review article contributions have been …
and define highly efficient synthetic tools. In this review article contributions have been …
Quantitative sustainability assessment of flow chemistry–from simple metrics to holistic assessment
Flow chemistry has changed chemical process designs toward process intensification and is
generally considered as green methodology. In this connection, this perspective provides a …
generally considered as green methodology. In this connection, this perspective provides a …
A biomass-derived safe medium to replace toxic dipolar solvents and access cleaner Heck coupling reactions
γ-Valerolactone (GVL) is an excellent reaction medium, derived from biomasses, which can
replace classic dipolar aprotic media such as DMF or NMP. In this contribution, we have …
replace classic dipolar aprotic media such as DMF or NMP. In this contribution, we have …
Glycerol carbonate as a versatile alkylating agent for the synthesis of β-aryloxy alcohols
G Galletti, P Prete, S Vanzini… - ACS Sustainable …, 2022 - ACS Publications
The possibility to use glycerol carbonate (GlyC) as an innovative alkylating agent for
phenolic compounds in solventless conditions and in the presence of a catalytic amount of …
phenolic compounds in solventless conditions and in the presence of a catalytic amount of …
Ring‐Opening of Epoxides in water
Epoxides and water mix well together. The use of water represents an intriguing alternative
to organic solvents, not only for developing green processes but also for exploring a totally …
to organic solvents, not only for developing green processes but also for exploring a totally …
Palladium Supported on Cross‐Linked Imidazolium Network on Silica as Highly Sustainable Catalysts for the Suzuki Reaction under Flow Conditions
C Pavia, E Ballerini, LA Bivona… - Advanced Synthesis …, 2013 - Wiley Online Library
Highly cross‐linked imidazolium‐based materials, obtained by radical oligomerization of bis‐
vinylimidazolium salts in the presence of 3‐mercaptopropyl‐modified silica gel, were used …
vinylimidazolium salts in the presence of 3‐mercaptopropyl‐modified silica gel, were used …
Continuous flow/waste-minimized synthesis of benzoxazoles catalysed by heterogeneous manganese systems
Herein, we present our results on the development of a waste minimized protocol for the
synthesis of 2-arylbenzoxazoles in continuous flow. Manganese-based heterogeneous …
synthesis of 2-arylbenzoxazoles in continuous flow. Manganese-based heterogeneous …
Sc (III)-catalyzed enantioselective addition of thiols to α, β-unsaturated ketones in neutral water
This report concerns Lewis acid catalyzed enantioselective sulfa-Michael addition in neutral
water by using a very efficient Sc (OTf) 3/bipyridine 1 catalytic system. It is noteworthy that …
water by using a very efficient Sc (OTf) 3/bipyridine 1 catalytic system. It is noteworthy that …
Mass efficiency of alkene syntheses with tri-and tetrasubstituted double bonds
M Eissen, D Lenoir - ACS Sustainable Chemistry & Engineering, 2017 - ACS Publications
Environmental factors and process mass intensity were determined and evaluated for more
than 30 standard procedures for the synthesis of alkenes with tri-and tetrasubstituted double …
than 30 standard procedures for the synthesis of alkenes with tri-and tetrasubstituted double …