N-Triflylphosphoramides (NTPA), have become increasingly popular catalysts in the
development of enantioselective transformations as they are stronger Brønsted acids than …

Nickel complexes bearing chiral diphosphine ligands, such as (S)-Tol-MeO-BIPHEP and (S)-
H 8-BINAP, serve as efficient catalysts for asymmetric allylic alkylation (AAA) of β-ketoesters …

The mode of asymmetric induction in an enantioselective intramolecular allylic substitution
reaction catalyzed by a combination of palladium and a chiral phosphoric acid was …

The role of allylic substitution reactions is crucial in organic synthesis. Through these
reactions, the development of numerous molecular structures with a wide range of …

A complementary copper-catalyzed and electrochemical aminosulfonylation of O-homoallyl
benzimidates and N-alkenyl amidines with sodium sulfinates was developed. The terminal …

A highly enantioselective synthesis of 1, 4‐enynes is described that proceeds through an
organocatalytic reaction between propargyl alcohols and trialkenylboroxines. Our strategy …

A highly efficient kinetic resolution (KR) of racemic tertiary allylic alcohols was achieved
through an intramolecular allylic substitution reaction using a co-catalyst system composed …

Control over chemo-and regioselectivity is a critical issue in the heterobiaryl synthesis via C–
H oxidative coupling. To address this challenge, a strategy to invert the normal polarity of …

An asymmetric catalytic approach for the construction of C3-multifunctionalization α-hydroxy-
β-amino pyridines has been reported. The products can be accessed by the modulation of …

An enantioselective formal α-vinylation of ketones for the construction of an all-carbon
quaternary center was established using the vinylogous Wagner–Meerwein shift through the …