Structure–reactivity–property relationships in covalent adaptable networks
V Zhang, B Kang, JV Accardo… - Journal of the American …, 2022 - ACS Publications
Polymer networks built out of dynamic covalent bonds offer the potential to translate the
control and tunability of chemical reactions to macroscopic physical properties. Under …
control and tunability of chemical reactions to macroscopic physical properties. Under …
Covalent mechanochemistry and contemporary polymer network chemistry: a marriage in the making
Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of
mechanophores that translate mechanical energy into a variety of functional responses …
mechanophores that translate mechanical energy into a variety of functional responses …
Mechanically triggered carbon monoxide release with turn-on aggregation-induced emission
Polymers that release functional small molecules under mechanical stress potentially serve
as next-generation materials for catalysis, sensing, and mechanochemical dynamic therapy …
as next-generation materials for catalysis, sensing, and mechanochemical dynamic therapy …
Naphthopyran molecular switches and their emergent mechanochemical reactivity
Naphthopyran molecular switches undergo a ring-opening reaction upon external
stimulation to generate intensely colored merocyanine dyes. Their unique modularity and …
stimulation to generate intensely colored merocyanine dyes. Their unique modularity and …
Release of molecular cargo from polymer systems by mechanochemistry
R Küng, R Göstl, BM Schmidt - Chemistry–A European Journal, 2022 - Wiley Online Library
The design and manipulation of (multi) functional materials at the nanoscale holds the
promise of fuelling tomorrow's major technological advances. In the realm of …
promise of fuelling tomorrow's major technological advances. In the realm of …
Strain‐Driven Formal [1, 3]‐Aryl Shift within Molecular Bows
L Jiang, Z Peng, Y Liang, ZB Tang… - Angewandte Chemie …, 2023 - Wiley Online Library
Delving into the influence of strain on organic reactions in small molecules at the molecular
level can unveil valuable insight into developing innovative synthetic strategies and …
level can unveil valuable insight into developing innovative synthetic strategies and …
Mechanochemically accessing a challenging-to-synthesize depolymerizable polymer
TG Hsu, S Liu, X Guan, S Yoon, J Zhou… - Nature …, 2023 - nature.com
Polymers with low ceiling temperatures (T c) are highly desirable as they can depolymerize
under mild conditions, but they typically suffer from demanding synthetic conditions and poor …
under mild conditions, but they typically suffer from demanding synthetic conditions and poor …
Furan release via force-promoted retro-[4+ 2][3+ 2] cycloaddition
K Suwada, AW Ieong, HLH Lo… - Journal of the American …, 2023 - ACS Publications
Mechanophores (mechanosensitive molecules) have been instrumental in the development
of various force-controlled release systems. However, the release of functional organic …
of various force-controlled release systems. However, the release of functional organic …
Leveraging mechanochemistry for sustainable polymer degradation
S Aydonat, AH Hergesell, CL Seitzinger, R Lennarz… - Polymer Journal, 2024 - nature.com
Over 8 billion tons of plastic have been produced to date, and a 100% reclamation recycling
strategy is not foreseeable. This review summarizes how the mechanochemistry of polymers …
strategy is not foreseeable. This review summarizes how the mechanochemistry of polymers …
Bringing quantum mechanics to coarse-grained soft materials modeling
CI Wang, NE Jackson - Chemistry of Materials, 2023 - ACS Publications
Fundamental knowledge gaps are endemic in our understanding of how emergent
properties of soft materials are linked to the quantum mechanical (QM) world. The limitations …
properties of soft materials are linked to the quantum mechanical (QM) world. The limitations …