Titanium‐Oxo Clusters with Bi‐and Tridentate Organic Ligands: Gradual Evolution of the Structures from Small to Big

U Schubert - Chemistry–A European Journal, 2021 - Wiley Online Library
Homometallic titanium oxo clusters are one of the most important groups of metal oxo
clusters, with more than 300 examples characterized by X‐ray structure analyses. Most of …

Aggregation of titanium‐oxo clusters

YL Xie, WH Fang, J Zhang - Aggregate, 2024 - Wiley Online Library
Compared with nanoparticle‐aspect relatives titanium dioxide (TiO2), titanium‐oxo clusters
(TOCs) are atomically structural‐determined and can be further precisely modified through …

Titanium phosphonate oxo-alkoxide “clusters”: solution stability and facile hydrolytic transformation into nano titania

FG Svensson, G Daniel, CW Tai, GA Seisenbaeva… - RSC …, 2020 - pubs.rsc.org
Titanium (oxo-) alkoxide phosphonate complexes were synthesized using different titanium
precursors and tert-butylphosphonic acid (tBPA) as molecular models for interaction …

A review of phosphorus (V)-substituted titanium-oxo clusters

R Hayami, T Gunji - Journal of Sol-Gel Science and Technology, 2021 - Springer
Abstract Phosphorus (V)-substituted titanium-oxo clusters are composed of titanoxane (Ti–O–
Ti), phosphatitanoxane (Ti–O–P), and organic/inorganic groups, such as …

Syntheses and properties of Cu (II), Al (III), and Ti (IV) coordination polymers using an acetylacetonato-terminated polyhedral oligomeric silsesquioxane

Y Sato, R Hayami, K Yamamoto, T Gunji - Polymer Journal, 2022 - nature.com
Synthesis of coordination polymers based on polyhedral oligomeric silsesquioxane (POSS)
has attracted attention as an important research direction because POSS-based polymers …

4-Chlorosalicylate-stabilized titanium-oxo clusters with structures mediated by tetrazole and their photophysical properties

Y Cui, GD Zou, HM Li, Y Huang, Y Fan - Polyhedron, 2019 - Elsevier
Abstract Three 4-chlorosalicylate-stabilized titanium-oxo clusters (TOCs), namely, H 2 [Ti 4
(μ 2-O)(μ 2-OiPr) 2 (OiPr) 6 (ClSal) 4](ClSal= 4-chlorosalicylate), H [Ti 11 (μ 3-O) 7 (μ 2-O) 2 …

Characterization of a flexible self-cleaning film with photoinduced hydrophilicity comprising phosphonic-acid-modified polysilsesquioxane-anchored titanium dioxide

W Nakamoto, R Hayami, S Aizawa, Y Miyase, S Fujii… - Thin Solid Films, 2020 - Elsevier
Self-cleaning materials with photoinduced hydrophilicity have received significant attention.
These materials have been applied to rigid and flat substrates such as glasses and …

Organic–inorganic hybrids based on poly(bisphenol A-co-epichlorohydrin) containing titanium phosphonate clusters

R Hayami, W Nakamoto, Y Sato, K Yamamoto… - Polymer journal, 2019 - nature.com
Organic–inorganic hybrid films were prepared by transalkoxylation of poly (bisphenol A-co-
epichlorohydrin)(PBE) and titanium phosphonate clusters, such as [Ti4 (μ3-O)(O i Pr) 5 (μ-O …

Properties and surface morphologies of organic–inorganic hybrid thin films containing titanium phosphonate clusters

R Hayami, K Wada, Y Miyase, T Sagawa, S Tsukada… - Polymer …, 2018 - nature.com
Organic–inorganic hybrid thin films containing [Ti4 (μ 3-O)(O i Pr) 5 (μ-O i Pr) 3 (O3PPh) 3]·
THF (TiOPPh) were prepared via the hybridization of TiOPPh with poly (vinyl phenol)(PVP) …

Sol–gel reaction of titanium phosphonate alkoxide cluster

H Tsukagoshi, Y Sato, K Yamamoto… - Applied …, 2022 - Wiley Online Library
The synthesis and properties of titanium phosphonate cluster molecules have been
investigated; however, nothing has been done to study not only the catalytic ability of a …