State-of-the-art and recent progress in resorcinarene-based cavitand

K Wang, Q Liu, L Zhou, H Sun, X Yao, XY Hu - Chinese Chemical Letters, 2023 - Elsevier
Compartmentalization in the biological world brings excellent efficiency and specificity to the
formation of complex compounds, inspiring supramolecular chemists to continuously search …

Chiral supramolecular polymer formed via host-guest complexation of an octaphosphonate biscavitand and a chiral diammonium guest

K Hamada, D Shimoyama, T Hirao… - Bulletin of the Chemical …, 2022 - academic.oup.com
Chiral supramolecular polymers were constructed through the host-guest complexation of
an octaphosphonate biscavitand and a chiral diammonium guest. Isothermal titration …

Feet‐to‐Feet‐Connected Multitopic Resorcinarene Macrocycles

D Shimoyama, T Haino - Asian Journal of Organic Chemistry, 2020 - Wiley Online Library
The past three decades have witnessed extraordinary advances in the preparation of
macrocycles from a resorcinarene platform. Bridging two or more resorcinarene units …

Designing the disorder: the kinetics of nonisothermal crystallization of the orientationally disordered crystalline phase in a nematic mesogen

T Rozwadowski, M Jasiurkowska-Delaporte… - Physical Chemistry …, 2020 - pubs.rsc.org
This article presents the molecular dynamics and solidification behavior of a 2, 3-difluoro-4-
propylphenyl 2, 3-difluoro-4-(4-pentylcyclohexyl) benzoate nematic liquid crystal (5C4FPB3) …

Entropy‐Driven Cooperativity in the Guest Binding of an Octaphosphonate Bis‐cavitand

D Shimoyama, T Haino - Chemistry–A European Journal, 2020 - Wiley Online Library
Uncommon entropy‐driven cooperativity is reported in the guest binding of an
octaphosphonate bis‐cavitand. Isothermal titration calorimetry determined the …

Cooperativity in molecular recognition of feet-to-feet-connected biscavitands

T Haino - Pure and Applied Chemistry, 2023 - degruyter.com
Octaphosphonate biscavitand and self-folding deep biscavitand show strong positive and
negative cooperativity, respectively. The mechanism of the cooperativity is discussed in …

Resorcinarene-Based Supramolecular Capsules: Supramolecular Functions and Applications

R Sekiya, K Harada, N Nitta, T Haino - Synlett, 2022 - thieme-connect.com
A resorcinarene is a synthetic macrocycle consisting of four resorcinol molecules covalently
linked by methylene bridges. The interannular bridges produce a cavitand that has a bowl …

Unimolecular artificial transmembrane channels showing reversible ligand-gating behavior

Q Xiao, WW Haoyang, T Lin, ZT Li… - Chemical …, 2021 - pubs.rsc.org
A series of peptide-appended bisresorcinarenes were synthesized, which adopted tubular
conformation induced by intramolecular hydrogen bonds. The derivatives formed …

Supramolecular polymerization behavior of a ditopic self-folding biscavitand

H Fujimoto, T Hirao, T Haino - Bulletin of the Chemical Society of …, 2024 - academic.oup.com
Reported herein is the supramolecular polymerization of a mixture of a feet-to-feet
connected biscavitand and a homoditopic quinuclidinium guest that is regulated by …

Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand

D Shimoyama, R Sekiya, T Haino - Chemical Communications, 2020 - pubs.rsc.org
An octaiodobiscavitand was synthesized via an aromatic Finkelstein iodination reaction in
good yield. Sonogashira and Suzuki coupling reactions of the octaiodobiscavitand gave rise …