Advances in the use of CO 2 as a renewable feedstock for the synthesis of polymers

B Grignard, S Gennen, C Jérôme, AW Kleij… - Chemical Society …, 2019 - pubs.rsc.org
Carbon dioxide offers an accessible, cheap and renewable carbon feedstock for synthesis.
Current interest in the area of carbon dioxide valorisation aims at new, emerging …

Trends in non-isocyanate polyurethane (NIPU) development

A Gomez-Lopez, F Elizalde, I Calvo… - Chemical …, 2021 - pubs.rsc.org
The transition towards safer and more sustainable production of polymers has led to a
growing body of academic research into non-isocyanate polyurethanes (NIPUs) as potential …

Organocatalyzed coupling of carbon dioxide with epoxides for the synthesis of cyclic carbonates: catalyst design and mechanistic studies

M Alves, B Grignard, R Méreau, C Jerome… - Catalysis Science & …, 2017 - pubs.rsc.org
The coupling of carbon dioxide (CO2) with epoxides with the formation of cyclic carbonates
is a highly attractive 100% atom economic reaction. It represents a greener and safer …

A perspective approach to sustainable routes for non-isocyanate polyurethanes

A Cornille, R Auvergne, O Figovsky, B Boutevin… - European Polymer …, 2017 - Elsevier
Sustainable routes for the synthesis of polyurethanes with industrial applications are
discussed in this article. Polyurethane is currently one of the most commonly used polymers …

From the synthesis of biobased cyclic carbonate to polyhydroxyurethanes: a promising route towards renewable non‐isocyanate polyurethanes

C Carré, Y Ecochard, S Caillol, L Avérous - ChemSusChem, 2019 - Wiley Online Library
With a global production of around 18 million tons (6th among all polymers) and a wide
range of applications, such as rigid and soft foams, elastomers, coatings, and adhesives …

Poly (hydroxyurethane) adhesives and coatings: state-of-the-art and future directions

A Gomez-Lopez, S Panchireddy… - ACS Sustainable …, 2021 - ACS Publications
Polyurethane (PU) adhesives and coatings are widely used to fabricate high-quality
materials due to their excellent properties and their versatile nature, which stems from the …

Reprocessable polyhydroxyurethane networks exhibiting full property recovery and concurrent associative and dissociative dynamic chemistry via …

X Chen, L Li, K Jin, JM Torkelson - Polymer Chemistry, 2017 - pubs.rsc.org
We discovered that polyhydroxyurethane (PHU) networks synthesized in the presence of a
catalyst from five-membered cyclic carbonates are intrinsically reprocessable with full …

Hybrid polyhydroxyurethanes: How to overcome limitations and reach cutting edge properties?

Y Ecochard, S Caillol - European Polymer Journal, 2020 - Elsevier
The restrictions on isocyanate substances have encouraged researchers to find alternative
methods for the synthesis of Polyurethanes (PUs). New pathways have been designed with …

Opportunities for organocatalysis in polymer synthesis via step-growth methods

A Bossion, KV Heifferon, L Meabe, N Zivic… - Progress in Polymer …, 2019 - Elsevier
Organocatalysis has emerged as an invaluable tool for polymer synthesis and has already
demonstrated versatility for replacing organometallic catalysts in many polymerization …

Assessment of plant and microalgal oil-derived nonisocyanate polyurethane products for potential commercialization

T Dong, E Dheressa, M Wiatrowski… - ACS Sustainable …, 2021 - ACS Publications
Green pathways for nonisocyanate polyurethane (NIPU) production have attracted
increasing levels of interest. The reaction between 5-membered cyclic carbonate and …