Carbon–sulfur bond cross-coupling has become more and more attractive as an alternative
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …

Cu-catalysed arylation reactions devoted to the formation of C–C and C–heteroatom bonds
(Ullmann-type couplings) have acquired great importance in the last decade. This review …

Arylraryl bond formation is one of the most important tools of modern organic synthesis.
These bonds are very often found in natural products such as alkaloids as well as in …

Natural product synthesis is a highly demanding field in constant need of efficient
transformations that allow either straightforward, scalable, and high-yielding preparation of …

C–S bond activation, cleavage and transformations by means of transition metal compounds
have recently become more and more important in the petroleum industry and synthetic …

In the last decade, a number of methods using various copper complexes and salts to carry
out cross-coupling reactions leading to the formation of Cheteroatom (CN, CO, CS, CP …

Eighteen years ago in Angewandte Chemie John K. Stille reviewed a novel methodology,
which eventually became known by his name, for the coupling of organostannanes with …

An experimentally simple and inexpensive catalyst system was developed for the amidation
of aryl halides by using 0.2− 10 mol% of CuI, 5− 20 mol% of a 1, 2-diamine ligand, and …

First-row transition-metal-mediated reactions constitute an important and growing area of
research due to the low cost, low toxicity, and exceptional synthetic versatility of these …

Highly discriminating activation of a stable carbon-sulfur bond is achieved in the presence of
a vast sea of oxygen and nitrogen heteroatoms in various biochemical transformations. 1, 2 …