Bending the planar trigonal boron center of triphenylborane by connecting its aryl rings with
carbon or phosphorus linkers gave access to a series of 9‐boratriptycene derivatives with …

In this combined experimental and theoretical study, a computational protocol is reported to
predict the excited states in D‐π‐A compounds containing the B (FXyl) 2 (FXyl= 2, 6‐bis …

Nonclassical P (III) centers have attracted much attention in recent years. Incorporating a P
(III) center in a rigid bicyclic platform offers a particularly attractive way to invoke significant …

Three different perfluoroalkylated borafluorenes (FBf) were prepared and their electronic
and photophysical properties were investigated. The systems have four trifluoromethyl …

Recently, the choice of ligand and geometric control of mononuclear complexes, which can
affect the relaxation pathways and blocking temperature, have received wide attention in the …

Phosphasilatriptycene, a phenylene spacer and a pyridyl moiety represent the building
blocks of TRIP-Py, the first heteroditopic ligand featuring a phoshatriptycene scaffold. The P …

Although boron Lewis acids commonly adopt a trigonal planar geometry, a number of
compounds in which the trivalent boron atom is located in a pyramidal environment have …

A series of zwitterionic nickel (II) compounds with anionic diphosphine ligands having varied
substituents have been synthesized and studied as catalysts for CO-ethylene …

Using a new divergent approach, conjugated triarylborane dendrimers were synthesized up
to the 2nd generation. The synthetic strategy consists of three steps: 1) functionalization, via …

Two practical and high-yielding syntheses of 9-phosphatriptycene are reported. In both
approaches, the key step is based on the cyclization of a (tris) lithio-triphenylmethane or a …