Metal–metal bond in lanthanide single-molecule magnets
Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …
Symmetry strategies for high performance lanthanide-based single-molecule magnets
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …
Molecular magnetic hysteresis at 60 kelvin in dysprosocenium
Lanthanides have been investigated extensively for potential applications in quantum
information processing and high-density data storage at the molecular and atomic scale …
information processing and high-density data storage at the molecular and atomic scale …
High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium (III) metallocenium single-molecule magnets
KR McClain, CA Gould, K Chakarawet, SJ Teat… - Chemical …, 2018 - pubs.rsc.org
A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
Single-molecule magnets beyond a single lanthanide ion: the art of coupling
YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …
On approaching the limit of molecular magnetic anisotropy: a near‐perfect pentagonal bipyramidal dysprosium (III) single‐molecule magnet
YS Ding, NF Chilton, REP Winpenny… - Angewandte Chemie …, 2016 - Wiley Online Library
We report a monometallic dysprosium complex,[Dy (OtBu) 2 (py) 5][BPh4](5), that shows the
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …
A stable pentagonal bipyramidal Dy (III) single-ion magnet with a record magnetization reversal barrier over 1000 K
Single-molecule magnets (SMMs) with a large spin reversal barrier have been recognized to
exhibit slow magnetic relaxation that can lead to a magnetic hysteresis loop. Synthesis of …
exhibit slow magnetic relaxation that can lead to a magnetic hysteresis loop. Synthesis of …
Symmetry-supported magnetic blocking at 20 K in pentagonal bipyramidal Dy (III) single-ion magnets
Single-molecule magnets (SMMs) that can be trapped in one of the bistable magnetic states
separated by an energy barrier are among the most promising candidates for high-density …
separated by an energy barrier are among the most promising candidates for high-density …
Emerging trends on designing high-performance dysprosium (III) single-molecule magnets
TG Ashebr, H Li, X Ying, XL Li, C Zhao, S Liu… - ACS Materials …, 2022 - ACS Publications
The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …
Molecular magnetism of lanthanide: Advances and perspectives
Z Zhu, M Guo, XL Li, J Tang - Coordination Chemistry Reviews, 2019 - Elsevier
The discovery of the first example of lanthanide-based single molecule magnets (Ln-SMMs),
a revolutionary progress, marked the beginning of a new age for SMMs, has greatly inspired …
a revolutionary progress, marked the beginning of a new age for SMMs, has greatly inspired …