Direct decarboxylative Giese reactions
DM Kitcatt, S Nicolle, AL Lee - Chemical Society Reviews, 2022 - pubs.rsc.org
The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …
Recent Advances in Photoredox‐Mediated Radical Conjugate Addition Reactions: An Expanding Toolkit for the Giese Reaction
AL Gant Kanegusuku, JL Roizen - … Chemie International Edition, 2021 - Wiley Online Library
Photomediated Giese reactions are at the forefront of radical chemistry, much like the
classical tin‐mediated Giese reactions were nearly forty years ago. With the global …
classical tin‐mediated Giese reactions were nearly forty years ago. With the global …
[HTML][HTML] Graphene/inorganic nanocomposites: Evolving photocatalysts for solar energy conversion for environmental remediation
Current energy crisis and environmental issues, including depletion of fossil fuels, rapid
industrialization, and undesired CO 2 emission resulting in global warming has created …
industrialization, and undesired CO 2 emission resulting in global warming has created …
Free carboxylic acids: the trend of radical decarboxylative functionalization
L Li, Y Yao, N Fu - European Journal of Organic Chemistry, 2023 - Wiley Online Library
The exceptional versatility of carboxylic acids has been extensively exploited in organic
synthesis across several decades. There has been a recent upsurge of radical …
synthesis across several decades. There has been a recent upsurge of radical …
Direct decarboxylative Giese amidations: photocatalytic vs. metal-and light-free
DM Kitcatt, KA Scott, E Rongione, S Nicolle… - Chemical Science, 2023 - pubs.rsc.org
A direct intermolecular decarboxylative Giese amidation reaction from bench stable, non-
toxic and environmentally benign oxamic acids has been developed, which allows for easy …
toxic and environmentally benign oxamic acids has been developed, which allows for easy …
A comprehensive survey upon diverse and prolific applications of chitosan-based catalytic systems in one-pot multi-component synthesis of heterocyclic rings
H Mousavi - International Journal of Biological Macromolecules, 2021 - Elsevier
Heterocyclic compounds are among the most prestigious and valuable chemical molecules
with diverse and magnificent applications in various sciences. Due to the remarkable and …
with diverse and magnificent applications in various sciences. Due to the remarkable and …
Lewis Acid Activation of Fragment-Coupling Reactions of Tertiary Carbon Radicals Promoted by Visible-Light Irradiation of EDA Complexes
SP Pitre, TK Allred, LE Overman - Organic Letters, 2021 - ACS Publications
The addition of tertiary carbon radicals generated from N-(acyloxy) phthalimide esters to
cyclic α, β-unsaturated ketones and lactones is markedly enhanced by the addition of …
cyclic α, β-unsaturated ketones and lactones is markedly enhanced by the addition of …
Reactivity of Superbasic Carbanions Generated via Reductive Radical‐Polar Crossover in the Context of Photoredox Catalysis
S Grotjahn, C Graf, J Zelenka… - Angewandte Chemie …, 2024 - Wiley Online Library
Photocatalytic reactions involving a reductive radical‐polar crossover (RRPCO) generate
intermediates with carbanionic reactivity. Many of these proposed intermediates resemble …
intermediates with carbanionic reactivity. Many of these proposed intermediates resemble …
Photoinduced Decarboxylative Radical Coupling Reaction of Multiply Oxygenated Structures by Catalysis of Pt-Doped TiO2
D Kuwana, Y Komori, M Nagatomo… - The Journal of Organic …, 2021 - ACS Publications
A new reaction system was devised for decarboxylative radical coupling reactions by
heterogeneous semiconductor photoredox catalysis. When an α-alkoxy carboxylic acid and …
heterogeneous semiconductor photoredox catalysis. When an α-alkoxy carboxylic acid and …
Photomediated Hydro (deutero) acylation of Olefins by Decarboxylative Addition of α-Oxocarboxylic Acids
F Gao, ZY Liao, YH Ye, QH Yu, C Yang… - The Journal of …, 2024 - ACS Publications
Acyl radicals have been generated from the decarboxylation of α-oxocarboxylic acids by
using a readily accessible organic pyrimidopteridine photoredox catalyst under ultraviolet-A …
using a readily accessible organic pyrimidopteridine photoredox catalyst under ultraviolet-A …