Advances in carbohydrate chemistry have certainly made common oligosaccharides much
more accessible. However, many current methods still rely heavily upon specialized …

Catalytic glycosylation has been a central reaction in carbohydrate chemistry since its
introduction by Fischer 125 years ago, but it is only in the past three to four decades that …

The development of glycobiology relies on the sources of particular oligosaccharides in their
purest forms. As the isolation of the oligosaccharide structures from natural sources is not a …

Oligosaccharides are ubiquitous in molecular biology and are used for functions ranging
from governing protein folding to intercellular communication. Perhaps paradoxically, the …

The methodological developments in gold (I)-and gold (III)-catalyzed glycosylation reactions
are fully surveyed, which exploit the special alkynophilicity or the Lewis acidity of the gold …

In this paper, a visible-light-promoted cross-coupling of 4-alkyl-1, 4-dihydropyridines with
thio-/selenium sulfonates under transition-metal-free conditions is described. This strategy …

An effective regiodivergent synthesis toward 1-and 3-thiosugars was achieved through
palladium and cobalt catalysis, respectively. β-1-Thiosugars were obtained from 3, 4-O …

We herein present a strain-release glycosylation method employing a rationally designed
ortho-2, 2-dimethoxycarbonylcyclopropylbenzyl (CCPB) thioglycoside donor. The donor is …

Palladium (II) in combination with a monodentate phosphine ligand enables the
unprecedented direct and α‐stereoselective catalytic synthesis of deoxyglycosides from …

An efficient synthesis of thioglycosides from per-acetates in the presence of triflic acid is
described. The developed protocol features high reaction rates and product yields. Some …