Metal–organic frameworks are a class of porous crystalline materials based on the ordered
connection of metal centers or metal clusters by organic linkers with comprehensive …

Dynamic processes are responsible for the functionality of a range of materials,
biomolecules, and catalysts. We report a detailed systematic study of the modulation of …

Engineering coordinated rotational motion in porous architectures enables the fabrication of
molecular machines in solids. A flexible two‐fold interpenetrated pillared Metal‐Organic …

We report that a newly developed type of triaryltriazine rotor, which bears bulky silyl moieties
on the para position of its peripheral phenylene groups, forms a columnar stacked clutch …

Free accessible confined space and loose interaction are crucial for most solid-state ionic
motions. Here, by using a near-spherical anion and a disc-shaped ammonium as two …

By modifying organic ligands of metal-organic framework with dipolar units, they turn
suitable for various applications, eg, in the field of sensor systems or switching of gas …

Controlling the rotation of carbon-carbon bonds, which is ubiquitous in organic molecules, to
create functionality has been a subject of interest for a long time. In this context, it would be …

Herein, we report radical chlorination of cubane-1, 4-dicarboxylic acid leading preferentially
to one monochlorinated cubane dicarboxylate (ca. 70%) that is accompanied by four …

We report multidynamic molecular rotations in crystals using a concave‐shape N‐
heterocyclic carbene (NHC) binuclear Au (I) complex rotor bearing pyrazine and …

The assembly by design of suitable molecular building blocks produces Metal-Organic
Frameworks (MOFs) and Porous Organic Polymers (POPs) architectures endowed with high …