Green chemistry in the synthesis of pharmaceuticals

S Kar, H Sanderson, K Roy, E Benfenati… - Chemical …, 2021 - ACS Publications
The principles of green chemistry (GC) can be comprehensively implemented in green
synthesis of pharmaceuticals by choosing no solvents or green solvents (preferably water) …

Recent advances in ring-opening of donor acceptor cyclopropanes using C-nucleophiles

K Ghosh, S Das - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
Ring-opening transformations of donor–acceptor cyclopropanes (DAC) with carbon-
centered nucleophiles is a simple, straight-forward approach to 1, 3-bifunctional compounds …

Green asymmetric organocatalysis

D Krištofíková, V Modrocká, M Mečiarová… - …, 2020 - Wiley Online Library
Asymmetric organocatalysis is becoming one of the main tools for the synthesis of chiral
compounds that are needed as medicines, crop protection agents, and other bioactive …

Chemical recycling of poly (bisphenol A carbonate)

JG Kim - Polymer Chemistry, 2020 - pubs.rsc.org
Plastics are excellent materials: they are light weight, long-lasting, easy to manufacture, and
relatively cheap. The ongoing development of new polymers and their production …

Diaryliodoniums as hybrid hydrogen-and halogen-bond-donating organocatalysts for the Groebke–Blackburn–Bienaymé reaction

MV Il'in, AA Sysoeva, AS Novikov… - The Journal of Organic …, 2022 - ACS Publications
Dibenziodolium and diphenyliodonium triflates display high catalytic activity for the
multicomponent reaction that leads to a series of imidazopyridines. Density functional theory …

Sulfonium and selenonium salts as noncovalent organocatalysts for the multicomponent Groebke–Blackburn–Bienaymé reaction

MV Il'in, AS Novikov, DS Bolotin - The Journal of Organic …, 2022 - ACS Publications
Sulfonium and selenonium salts, represented by S-aryl dibenzothiophenium and Se-aryl
dibenzoselenophenium triflates, were found to exhibit remarkable catalytic activity in the …

Recent advances in continuous-flow organocatalysis for process intensification

C De Risi, O Bortolini, A Brandolese… - Reaction Chemistry & …, 2020 - pubs.rsc.org
Chemistry in continuous-flow continues to attract attention from the community of synthetic
organic chemists due to its now well-recognized benefits including, inter alia, quick reaction …

Iodonium salts as efficient iodine (III)-based noncovalent organocatalysts for Knorr-type reactions

SN Yunusova, AS Novikov, NS Soldatova, MA Vovk… - RSC …, 2021 - pubs.rsc.org
Hypervalent iodine (III)-derivatives display higher catalytic activity than other aliphatic and
aromatic iodine (I)–or bromine (I)-containing substrates for a Knorr-type reaction of N-acetyl …

(Pre) association as a crucial step for computational prediction and analysis of the catalytic activity of σ-hole donating organocatalysts

DA Polonnikov, MV Il'in, YV Safinskaya… - Organic Chemistry …, 2023 - pubs.rsc.org
Based upon the experimentally obtained kinetic data on iodonium salt catalyzed
nucleophilic addition of isocyanide to imine leading to imidazopyridine species, a reliable …

The catalytic asymmetric intermolecular Prins reaction

CD Díaz-Oviedo, R Maji, B List - Journal of the American Chemical …, 2021 - ACS Publications
Despite their significant potential, catalytic asymmetric reactions of olefins with formaldehyde
are rare and metal-free approaches have not been previously disclosed. Here we describe …