Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Transition-metal-catalyzed cross-coupling reactions have been well-established as
indispensable tools in modern organic synthesis. One of the major research goals in cross …

Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis |
Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution …

Allene moieties with axial chirality are featured in many natural products with biological
activities. They also serve as unique building blocks in organic synthesis and as chiral …

Hydrogen‐atom transfer (HAT) counts amongst the most widely investigated routes to
carbon‐centered radicals. Intramolecular processes involving 1, 5‐HAT are widespread to …

A highly enantioselective synthesis of trisubstituted allenes has been achieved through Cu
(I)-catalyzed cross-coupling of aryldiazoalkanes and terminal alkynes with chiral …

The broad utility of cyclic structures accounts for the key roles that cycle-forming reactions
play in synthetic designs. Most of these reactions can be classified as either a cyclization of …

Substrates, bearing axial chirality, can cyclize intra-or inter-molecularly with concomitant
transfer of axial-to-central chirality to produce at least one stereocenter. In order to satisfy a …

A CuI-catalyzed synthesis of 1, 3-disubstituted allenes from 1-alkynes by the reaction with
various N-tosylhydrazones has been developed. This method, which uses readily available …

The construction of aromatic rings has become a key objective for organic chemists. While
several strategies have been developed for the functionalization of pre-formed aromatic …