The development of late-stage functionalization (LSF) methodologies, particularly C–H
functionalization, has revolutionized the field of organic synthesis. Over the past decade …

Palladium-catalyzed aerobic oxidation reactions have been the focus of industrial
application and extensive research efforts for nearly 60 years. A significant transition …

Catalytic C–H activation has emerged as a powerful tool for sustainable syntheses. In the
recent years, notable success was achieved with the development of cobalt-catalyzed C–H …

Manganese is found in the active center of numerous enzymes that operate by an outer-
sphere homolytic C–H cleavage. Thus, a plethora of bioinspired radical-based C–H …

Activation of aromatic C H bonds by a transition metal catalyst has received significant
attention in the synthetic chemistry community. In recent years, rapid and site‐selective …

Acylated amino acid ligands enabled ruthenium (II)-catalyzed C–H functionalizations with
excellent levels of meta-selectivity. The outstanding catalytic activity of the ruthenium (II) …

The activation of typically unreactive aromatic C–H bonds by transition-metal catalysis has
been receiving increased attention from the synthetic chemistry community in recent years …

Ruthenium (II) complexes have emerged as effective catalysts for C–H arylations of
tetrazolyl-substituted arenes by chelation assistance. Particularly, bifunctional additives …

Abstract Aerobic oxidative C H functionalizations of weakly coordinating benzoic acids
have been accomplished with versatile ruthenium (II) biscarboxylates under ambient oxygen …

Palladium-catalyzed cross-coupling reactions are indispensable tools in molecular
syntheses with numerous applications in academia and for the practitioners in the chemical …