Flexible and Extensive Platinum Ion Gel Condensers for Programmable Catalysis

TM Onn, KR Oh, DZ Adrahtas, JK Soeherman… - ACS …, 2023 - ACS Publications
Catalytic condensers composed of ion gels separating a metal electrode from a platinum-on-
carbon active layer were fabricated and characterized to achieve more powerful, high …

Catalytic resonance theory: the catalytic mechanics of programmable ratchets

MA Murphy, SR Gathmann, R Getman, L Grabow… - Chemical …, 2024 - pubs.rsc.org
Catalytic reaction networks of multiple elementary steps operating under dynamic conditions
via a programmed input oscillation are difficult to interpret and optimize due to reaction …

Dynamic Promotion of the Oxygen Evolution Reaction via Programmable Metal Oxides

SR Gathmann, CJ Bartel, LC Grabow… - ACS Energy …, 2024 - ACS Publications
Hydrogen gas is a promising renewable energy storage medium when produced via water
electrolysis, but this process is limited by the sluggish kinetics of the anodic oxygen …

Alumina–Titania Nanolaminate Condensers for Hot Programmable Catalysis

KR Oh, A Walton, JA Chalmers, JA Hopkins… - ACS Materials …, 2024 - ACS Publications
N anolaminates composed of thin alternating layers of Al2O3 and TiO2 (ATO) were
engineered by using atomic layer deposition as the dielectric material for a Pt-on-carbon …

Up up down down left right left right BA Start for the catalytic hackers of programmable materials

PJ Dauenhauer - Matter, 2023 - cell.com
The valuable information of catalysis for the past century has been the composition and
structure of high-performing catalytic materials. But a new class of programmable catalysts …

Cyclic Steady-State Simulation and Waveform Design for Dynamic/Programmable Catalysis

CC Tedesco, JR Kitchin, CD Laird - The Journal of Physical …, 2024 - ACS Publications
Dynamic catalysis is a novel and promising approach that aims to improve the catalyst
performance by modulating the binding energies of adsorbates to favor different reaction …

Catalytic resonance theory: Circumfluence of programmable catalytic loops

MA Murphy, SR Gathmann, CJ Bartel… - Journal of …, 2024 - Elsevier
Chemical reactions on heterogeneous catalyst surfaces exhibit complex networks of
elementary reactions with multiple pathways to fluid phase products, sometimes leading to …

Catalytic Resonance Theory: Forecasting the Flow of Programmable Catalytic Loops

M Murphy, K Noordhoek, S Gathmann, P Dauenhauer… - 2024 - chemrxiv.org
Chemical transformations on catalyst surfaces occur through series and parallel reaction
pathways. These complex networks and their behavior can be most simply evaluated …

Ultrathin Catalytic Condensers with engineered Pt/HfO2 interfaces for charge modulation

M Dakhchoune, K Groenhout, R Rana… - 2024 - chemrxiv.org
Catalytic condensers offer a flexible platform for programmable catalysis by modulating the
electronic properties of active sites through applied voltage. Constructed as metal-oxide …

Isopotential Titration for Quantifying Metal-Adsorbate Charge Transfer

J Hopkins, S Wang, KR Oh, B Page, J Canavan… - 2024 - chemrxiv.org
The extent of charge transfer between adsorbed reactants and a catalyst surface plays a key
role in determining binding energy and catalytic activity. Here, we describe the technique of …