Porphyrin-catalyzed electrochemical hydrogen evolution reaction. Metal-centered and ligand-centered mechanisms
HM Castro-Cruz, NA Macias-Ruvalcaba - Coordination Chemistry Reviews, 2022 - Elsevier
In the past few decades, several transition metal complexes have emerged as molecular
catalysts for the electrochemically triggered hydrogen evolution reaction (HER). The catalytic …
catalysts for the electrochemically triggered hydrogen evolution reaction (HER). The catalytic …
Recent advances in spectroelectrochemistry
The integration of two quite different techniques, conventional electrochemistry and
spectroscopy, into spectroelectrochemistry (SEC) provides a complete description of …
spectroscopy, into spectroelectrochemistry (SEC) provides a complete description of …
Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism
The development of more effective energy conversion processes is critical for global energy
sustainability. The design of molecular electrocatalysts for the hydrogen evolution reaction is …
sustainability. The design of molecular electrocatalysts for the hydrogen evolution reaction is …
Functional molecular switches involving tetrapyrrolic macrocycles
AG Martynov, EA Safonova, AY Tsivadze… - Coordination Chemistry …, 2019 - Elsevier
Porphyrins and phthalocyanines are well-known colourful compounds, which attract much
attention in various fields of science and technology, including the area of molecular …
attention in various fields of science and technology, including the area of molecular …
Highly stable and porous porphyrin-based zirconium and hafnium phosphonates–electron crystallography as an important tool for structure elucidation
T Rhauderwiek, H Zhao, P Hirschle, M Döblinger… - Chemical …, 2018 - pubs.rsc.org
The Ni-metallated porphyrin-based tetraphosphonic acid (Ni-tetra (4-phosphonophenyl)
porphyrin, Ni-H8TPPP) was used for the synthesis of highly porous metal phosphonates …
porphyrin, Ni-H8TPPP) was used for the synthesis of highly porous metal phosphonates …
Azanone (HNO): generation, stabilization and detection
HNO (nitroxyl, azanone), joined the 'biologically relevant reactive nitrogen species' family in
the 2000s. Azanone is impossible to store due to its high reactivity and inherent low stability …
the 2000s. Azanone is impossible to store due to its high reactivity and inherent low stability …
Crystalline and permanently porous porphyrin-based metal tetraphosphonates
T Rhauderwiek, K Wolkersdörfer… - Chemical …, 2018 - pubs.rsc.org
The new porphyrin-based tetraphosphonic acid (Ni-H8TPPP) was employed in the synthesis
of four isostructural MOFs of composition [M (Ni-H6TPPP)(H2O)], denoted CAU-29 (M= Mn …
of four isostructural MOFs of composition [M (Ni-H6TPPP)(H2O)], denoted CAU-29 (M= Mn …
Spectroelectrochemistry as a powerful technique for porphyrins/corroles derivatives electro-characterization: fundamentals and some examples
B Dozza, BM Rodrigues, I Tisoco, VB de Souza… - Microchemical …, 2022 - Elsevier
Porphyrins and corroles are at the same time very similar and distinct species. Porphyrins
are present in nature and are well known by scientists for almost two centuries (1840) …
are present in nature and are well known by scientists for almost two centuries (1840) …
Ligand noninnocence in nickel porphyrins: Nickel isobacteriochlorin formation under hydrogen evolution conditions
AG Maher, M Liu, DG Nocera - Inorganic Chemistry, 2019 - ACS Publications
An electron-deficient nickel porphyrin complex undergoes facile ring reduction to form a
nickel isobacteriochlorin complex under hydrogen evolution conditions. Spectroscopic …
nickel isobacteriochlorin complex under hydrogen evolution conditions. Spectroscopic …
Photo/redox-responsive 2D-Supramolecular assembly involving Cucurbit [8] uril and a star-shaped porphyrin tecton
The present paper reports on the formation and on the electrochemical/spectroscopic
characterization of inclusion complexes formed in aqueous media between cucurbit [7 or 8] …
characterization of inclusion complexes formed in aqueous media between cucurbit [7 or 8] …