In the past few decades, several transition metal complexes have emerged as molecular
catalysts for the electrochemically triggered hydrogen evolution reaction (HER). The catalytic …

The integration of two quite different techniques, conventional electrochemistry and
spectroscopy, into spectroelectrochemistry (SEC) provides a complete description of …

The development of more effective energy conversion processes is critical for global energy
sustainability. The design of molecular electrocatalysts for the hydrogen evolution reaction is …

Porphyrins and phthalocyanines are well-known colourful compounds, which attract much
attention in various fields of science and technology, including the area of molecular …

The Ni-metallated porphyrin-based tetraphosphonic acid (Ni-tetra (4-phosphonophenyl)
porphyrin, Ni-H8TPPP) was used for the synthesis of highly porous metal phosphonates …

HNO (nitroxyl, azanone), joined the 'biologically relevant reactive nitrogen species' family in
the 2000s. Azanone is impossible to store due to its high reactivity and inherent low stability …

The new porphyrin-based tetraphosphonic acid (Ni-H8TPPP) was employed in the synthesis
of four isostructural MOFs of composition [M (Ni-H6TPPP)(H2O)], denoted CAU-29 (M= Mn …

Porphyrins and corroles are at the same time very similar and distinct species. Porphyrins
are present in nature and are well known by scientists for almost two centuries (1840) …

An electron-deficient nickel porphyrin complex undergoes facile ring reduction to form a
nickel isobacteriochlorin complex under hydrogen evolution conditions. Spectroscopic …

The present paper reports on the formation and on the electrochemical/spectroscopic
characterization of inclusion complexes formed in aqueous media between cucurbit [7 or 8] …