Promises and challenges of next-generation “beyond Li-ion” batteries for electric vehicles and grid decarbonization
The tremendous improvement in performance and cost of lithium-ion batteries (LIBs) have
made them the technology of choice for electrical energy storage. While established battery …
made them the technology of choice for electrical energy storage. While established battery …
Oxide cathodes: functions, instabilities, self healing, and degradation mitigations
Recent progress in high-energy-density oxide cathodes for lithium-ion batteries has pushed
the limits of lithium usage and accessible redox couples. It often invokes hybrid anion-and …
the limits of lithium usage and accessible redox couples. It often invokes hybrid anion-and …
Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries
Abstract High-entropy (HE) ceramics, by analogy with HE metallic alloys, are an emerging
class of solid solutions composed of a large number of species. These materials offer the …
class of solid solutions composed of a large number of species. These materials offer the …
Li-rich cathodes for rechargeable Li-based batteries: reaction mechanisms and advanced characterization techniques
Due to their high specific capacities beyond 250 mA hg− 1, lithium-rich oxides have been
considered as promising cathodes for the next generation power batteries, bridging the …
considered as promising cathodes for the next generation power batteries, bridging the …
Cation-disordered rocksalt transition metal oxides and oxyfluorides for high energy lithium-ion cathodes
For lithium-ion rechargeable batteries to meet society's ever-growing demands in electrical
energy storage, eg for the electrification of transportation, for portable electronics and for grid …
energy storage, eg for the electrification of transportation, for portable electronics and for grid …
Multi-anionic and-cationic compounds: new high entropy materials for advanced Li-ion batteries
In the present work, a new class of high entropy materials for energy storage applications is
introduced. Multi-anionic and-cationic compounds are prepared by facile mechanochemistry …
introduced. Multi-anionic and-cationic compounds are prepared by facile mechanochemistry …
Al‐doping driven suppression of capacity and voltage fadings in 4d‐element containing Li‐ion‐battery cathode materials: Machine learning and density functional …
The anion redox reaction in high‐energy‐density cathode materials such as Li‐excess
layered oxides suffers from voltage/capacity fadings due to irreversible structural instability …
layered oxides suffers from voltage/capacity fadings due to irreversible structural instability …
Electrochemical ion insertion from the atomic to the device scale
Electrochemical ion insertion involves coupled ion–electron transfer reactions, transport of
guest species and redox of the host. The hosts are typically anisotropic solids with 2D …
guest species and redox of the host. The hosts are typically anisotropic solids with 2D …
Design principles for zero-strain Li-ion cathodes
The cycling of cathode materials for Li-ion batteries is often accompanied by a change in
volume, posing a challenge to the integrity of cathode particles and electrolyte/cathode …
volume, posing a challenge to the integrity of cathode particles and electrolyte/cathode …
Fundamentals of ion‐exchange synthesis and its implications in layered oxide cathodes: recent advances and perspective
Layered oxide cathodes such as Ni‐rich ternary and Li‐rich layered cathode materials have
been widely used for lithium‐ion batteries owing to their excellent Li+ transport properties …
been widely used for lithium‐ion batteries owing to their excellent Li+ transport properties …