Isolation of (Aryl)‐(Imino) Phosphide and (Aryl)‐(Phosphaalkene) Amide Complexes of Alkali Metals from Carbene‐Phosphinidenes under Reductive‐Thermal …
Two‐electron reduction of cyclic alkyl (amino) carbene (cAAC)‐supported chloro‐
phosphinidene cAAC= P− Cl (1) followed by unprecedented thermal rearrangements …
phosphinidene cAAC= P− Cl (1) followed by unprecedented thermal rearrangements …
Argentophilic Interactions, Flexibility, and Dynamics of Pyrrole Cages Encapsulating Silver (I) Clusters
B Trzaskowski, JP Martínez, A Sarwa… - The Journal of …, 2024 - ACS Publications
Recently, pyrrole cages have been synthesized that encapsulate ion pairs and silver (I)
clusters to form intricate supramolecular capsules. We report here a computational analysis …
clusters to form intricate supramolecular capsules. We report here a computational analysis …
Monoanionic Phosphorus‐Supported Air Stable Cu(I)8, Ag(I)7, and Ag(I)5 Nanoclusters Exhibiting TADF: A Novel Photocatalyst for Stereoselective Carbene …
Applications of structurally well‐defined coinage‐metal nanoclusters (NCs) as
optoelectronic materials and homogeneous catalysts have been restricted due to their …
optoelectronic materials and homogeneous catalysts have been restricted due to their …
Isolation of Mixed Valence Charge-Neutral Ag 12, and Dicationic Ag 10 Nano-Clusters Stabilized by Carbene-Phosphaalkenides
M Francis, A Patra, FA Salam, SJ Prathapa… - Chemical …, 2025 - pubs.rsc.org
Cyclic alkyl (amino) carbene (cAAC)-supported phosphaalkenides (cAAC= P)-have been
employed as ligands for the isolation of two atomically precise mixed valence paramagnetic …
employed as ligands for the isolation of two atomically precise mixed valence paramagnetic …
Coordination Chemistry of Bis‐Cyclic Alkyl(Amino) Carbene (cAAC)‐Supported Di‐Phosphorus (P2): An Efficient Route to Donor Base‐Stabilized Elusive Di‐Phosphorus …
The stability and reactivity studies of heavier di‐atomic group‐15 congeners of alkynes, eg,
the di‐phosphorus (P≡ P) compounds have been the topic of huge interest because of their …
the di‐phosphorus (P≡ P) compounds have been the topic of huge interest because of their …
Reactivity Studies of Cyclic Alkyl (Amino) Carbene (cAAC)‐Supported Phosphinidenide with AuCl
A neutral octa‐nuclear AuI‐cluster (2) with molecular formula [(Cy‐cAACPAu) 4 (AuCl) 4][Cy‐
cAAC=: C (N‐2, 6‐iPr2C6H3)(C6H10)(CMe2)(CH2)] has been isolated, and structurally …
cAAC=: C (N‐2, 6‐iPr2C6H3)(C6H10)(CMe2)(CH2)] has been isolated, and structurally …