Reaction kinetics determination based on microfluidic technology

Z Yan, J Tian, C Du, J Deng, G Luo - Chinese Journal of Chemical …, 2022 - Elsevier
Microfluidic technology has been successfully applied to determine the reaction kinetics
relying on its great characteristics including narrow residence time distribution, fast mixing …

Advanced real‐time process analytics for multistep synthesis in continuous flow

P Sagmeister, R Lebl, I Castillo, J Rehrl… - Angewandte Chemie …, 2021 - Wiley Online Library
In multistep continuous flow chemistry, studying complex reaction mixtures in real time is a
significant challenge, but provides an opportunity to enhance reaction understanding and …

Revisiting aromatic diazotization and aryl diazonium salts in continuous flow: highlighted research during 2001–2021

J Chen, X Xie, J Liu, Z Yu, W Su - Reaction Chemistry & Engineering, 2022 - pubs.rsc.org
Aryl diazonium salts play an important role in chemical transformations; however their
explosive nature limits their applications in batch. Continuous flow technology allows safer …

Green and continuous aerobic oxidation of ethylbenzene over homogeneous and heterogeneous NHPI in a micro-packed bed reactor

C Zhang, J Luo, B Xie, W Liu, J Zhang - Chemical Engineering Journal, 2023 - Elsevier
Aerobic oxidation of ethylbenzene (EB) has emerged as a promising strategy for the
selective synthesis of acetophenone (AP) in line with green chemistry. The integration of …

Modern advancements in continuous-flow aided kinetic analysis

CJ Taylor, JA Manson, G Clemens, BA Taylor… - Reaction Chemistry & …, 2022 - pubs.rsc.org
Although kinetic analysis has traditionally been conducted in a batch vessel, continuous-
flow aided kinetic analysis continues to swell in popularity. This can be partly attributed to …

Copper/TEMPO-catalyzed continuous aerobic alcohol oxidation in a micro-packed bed reactor

C Zhang, X Duan, J Yin, F Lou, J Zhang - Reaction Chemistry & …, 2022 - pubs.rsc.org
Aerobic oxidation of alcohols to aldehydes and ketones provides a green and sustainable
method for the pharmaceutical and fragrance industries. For the industrial application of …

Green and practical TEMPO-functionalized activated carbon as a durable catalyst for continuous aerobic oxidation of alcohols

C Zhang, M Huang, J Yin, F Lou, X Chen, J Zhang - Journal of Catalysis, 2022 - Elsevier
The development of robust heterogeneous catalysts that can realize the aerobic oxidation of
alcohols in metal-free conditions is a profound challenge. Here, we report a reliable …

Continuous Hydrogenation of Maltose over Raney Ni in a Trickle-Bed Reactor

H Fan, Z Fang, X Zhao, Y Hu, B Li, W Yang… - Industrial & …, 2023 - ACS Publications
Maltitol has been identified as an important value-added chemical with versatile applications
and is typically manufactured via the catalytic hydrogenation of maltose, which is in urgent …

Hydrogenation kinetics of m-dinitrobenzene in a continuous micro-packed bed reactor

X Duan, J Yin, M Huang, A Feng, W Fu, H Chen… - Chemical Engineering …, 2022 - Elsevier
The hydrogenation of m-dinitrobenzene to m-phenylenediamine is a significant
transformation for the synthesis of dyes and pigments in the fine chemical industry. Owing to …

Alcoholysis of ethylene-vinyl acetate copolymer catalyzed by alkaline: A kinetic study based on in situ FTIR spectroscopy

Y He, H Ke, Y Lu - Chemical Engineering Journal, 2023 - Elsevier
Controlled alcoholysis of ethylene–vinyl acetate copolymer (EVA) is very important both to
industry and academic research. To this end, accurate kinetic model is an important tool, but …