MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

NF Suremann, BD McCarthy, W Gschwind… - Chemical …, 2023 - ACS Publications
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …

Redox-active metal–organic frameworks for energy conversion and storage

J Calbo, MJ Golomb, A Walsh - Journal of Materials Chemistry A, 2019 - pubs.rsc.org
Metal–organic frameworks (MOFs) are hybrid solids formed of organic and inorganic
building blocks. While the nature of electron addition, removal, and transport is well known …

Functionalized Zr-UiO-67 metal-organic frameworks: Structural landscape and application

AH Vahabi, F Norouzi, E Sheibani… - Coordination Chemistry …, 2021 - Elsevier
UiO based metal-organic frameworks (MOFs) have attracted much attention of many
scientists among the large family of Zirconium MOFs. UiO-series including UiO-66,-67 and …

Metal–organic frameworks as photocatalysts for solar-driven overall water splitting

S Navalón, A Dhakshinamoorthy, M Álvaro… - Chemical …, 2022 - ACS Publications
Metal–organic frameworks (MOFs) have been frequently used as photocatalysts for the
hydrogen evolution reaction (HER) using sacrificial agents with UV–vis or visible light …

The role of redox hopping in metal–organic framework electrocatalysis

S Lin, PM Usov, AJ Morris - Chemical Communications, 2018 - pubs.rsc.org
The dominant charge transfer mechanism in a vast number of metal–organic frameworks
(MOFs) is that of redox hopping, a process best explained through the motion of electrons …

A potential roadmap to integrated metal organic framework artificial photosynthetic arrays

B Gibbons, M Cai, AJ Morris - Journal of the American Chemical …, 2022 - ACS Publications
Metal organic frameworks (MOFs), a class of coordination polymers, gained popularity in the
late 1990s with the efforts of Omar Yaghi, Richard Robson, Susumu Kitagawa, and others …

Synthesis of core–shell ZIF-67@ Co-MOF-74 catalyst with controllable shell thickness and enhanced photocatalytic activity for visible light-driven water oxidation

C Guo, J Guo, Y Zhang, D Wang, L Zhang, Y Guo… - …, 2018 - pubs.rsc.org
In this paper, a core–shell ZIF-67@ Co-MOF-74 catalyst was synthesized by coating 2, 5-
dihydroxyterephthalic acid (DHTP) molecules on the surface of ZIF-67 crystals via the ligand …

Reaction intermediates in artificial photosynthesis with molecular catalysts

YH Hong, YM Lee, W Nam, S Fukuzumi - ACS Catalysis, 2022 - ACS Publications
In nature, water oxidation is catalyzed by Mn4Ca clusters in the oxygen-evolving complex
(OEC) of photosystem II (PSII), in which a manganese (V)-oxo species acts as an active …

Exposing coordination-unsaturated Co sites in Co-MOF for efficient photocatalytic water oxidation

JY Zhou, XY Guan, HP Zhang, D Luo… - Inorganic Chemistry …, 2024 - pubs.rsc.org
Water oxidation to molecular dioxygen driven by visible light is essential but difficult in solar
fuel production due to its sluggish reaction kinetics. Although the catalytic process is highly …