MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects
NF Suremann, BD McCarthy, W Gschwind… - Chemical …, 2023 - ACS Publications
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
Redox-active metal–organic frameworks for energy conversion and storage
Metal–organic frameworks (MOFs) are hybrid solids formed of organic and inorganic
building blocks. While the nature of electron addition, removal, and transport is well known …
building blocks. While the nature of electron addition, removal, and transport is well known …
Functionalized Zr-UiO-67 metal-organic frameworks: Structural landscape and application
AH Vahabi, F Norouzi, E Sheibani… - Coordination Chemistry …, 2021 - Elsevier
UiO based metal-organic frameworks (MOFs) have attracted much attention of many
scientists among the large family of Zirconium MOFs. UiO-series including UiO-66,-67 and …
scientists among the large family of Zirconium MOFs. UiO-series including UiO-66,-67 and …
Metal–organic frameworks as photocatalysts for solar-driven overall water splitting
S Navalón, A Dhakshinamoorthy, M Álvaro… - Chemical …, 2022 - ACS Publications
Metal–organic frameworks (MOFs) have been frequently used as photocatalysts for the
hydrogen evolution reaction (HER) using sacrificial agents with UV–vis or visible light …
hydrogen evolution reaction (HER) using sacrificial agents with UV–vis or visible light …
The role of redox hopping in metal–organic framework electrocatalysis
The dominant charge transfer mechanism in a vast number of metal–organic frameworks
(MOFs) is that of redox hopping, a process best explained through the motion of electrons …
(MOFs) is that of redox hopping, a process best explained through the motion of electrons …
A potential roadmap to integrated metal organic framework artificial photosynthetic arrays
Metal organic frameworks (MOFs), a class of coordination polymers, gained popularity in the
late 1990s with the efforts of Omar Yaghi, Richard Robson, Susumu Kitagawa, and others …
late 1990s with the efforts of Omar Yaghi, Richard Robson, Susumu Kitagawa, and others …
Synthesis of core–shell ZIF-67@ Co-MOF-74 catalyst with controllable shell thickness and enhanced photocatalytic activity for visible light-driven water oxidation
C Guo, J Guo, Y Zhang, D Wang, L Zhang, Y Guo… - …, 2018 - pubs.rsc.org
In this paper, a core–shell ZIF-67@ Co-MOF-74 catalyst was synthesized by coating 2, 5-
dihydroxyterephthalic acid (DHTP) molecules on the surface of ZIF-67 crystals via the ligand …
dihydroxyterephthalic acid (DHTP) molecules on the surface of ZIF-67 crystals via the ligand …
Reaction intermediates in artificial photosynthesis with molecular catalysts
YH Hong, YM Lee, W Nam, S Fukuzumi - ACS Catalysis, 2022 - ACS Publications
In nature, water oxidation is catalyzed by Mn4Ca clusters in the oxygen-evolving complex
(OEC) of photosystem II (PSII), in which a manganese (V)-oxo species acts as an active …
(OEC) of photosystem II (PSII), in which a manganese (V)-oxo species acts as an active …
Exposing coordination-unsaturated Co sites in Co-MOF for efficient photocatalytic water oxidation
JY Zhou, XY Guan, HP Zhang, D Luo… - Inorganic Chemistry …, 2024 - pubs.rsc.org
Water oxidation to molecular dioxygen driven by visible light is essential but difficult in solar
fuel production due to its sluggish reaction kinetics. Although the catalytic process is highly …
fuel production due to its sluggish reaction kinetics. Although the catalytic process is highly …