Pattern selection by material aging: Modeling chemical gardens in two and three dimensions
BC Batista, AZ Morris… - Proceedings of the …, 2023 - National Acad Sciences
Chemical gardens are complex, often macroscopic, structures formed by precipitation
reactions. Their thin walls compartmentalize the system and adjust in size and shape if the …
reactions. Their thin walls compartmentalize the system and adjust in size and shape if the …
Emergence of power-law particle size distribution in microfluidic calcium carbonate precipitation: An extended yule process with a ripening effect
J Xu, MT Balhoff - Physical Review Letters, 2023 - APS
Precipitation of calcium carbonate in bulk solutions is well known to result in a bell-shaped
or bimodal particle size distribution. However, it is unclear how the distribution behaves if …
or bimodal particle size distribution. However, it is unclear how the distribution behaves if …
Flow Control of Fronts by Radial Injection
The dynamics of A+ B→ C fronts is analyzed theoretically in the presence of passive
advection when A is injected radially into B at a constant inlet flow rate Q. We compute the …
advection when A is injected radially into B at a constant inlet flow rate Q. We compute the …
4D neutron imaging of solute transport and fluid flow in sandstone before and after mineral precipitation
P Shafabakhsh, B Cordonnier… - Water Resources …, 2024 - Wiley Online Library
In many geological systems, the porosity of rock or soil may evolve during mineral
precipitation, a process that controls fluid transport properties. Here, we investigate the use …
precipitation, a process that controls fluid transport properties. Here, we investigate the use …
Self-organization of layered inorganic membranes in microfluidic devices
Q Wang, MR Bentley, O Steinbock - The Journal of Physical …, 2017 - ACS Publications
Inorganic precipitate membranes play an important role in chemobrionics and origin of life
research. They can involve a range of catalytic materials, affect crystal habits, and show …
research. They can involve a range of catalytic materials, affect crystal habits, and show …
Archimedean spirals form at low flow rates in confined chemical gardens
We describe and study the formation of confined chemical garden patterns. At low flow rates
of injection of cobalt chloride solution into a Hele-Shaw cell filled with sodium silicate, the …
of injection of cobalt chloride solution into a Hele-Shaw cell filled with sodium silicate, the …
Fingering instability during mixing-driven precipitation flow
In this study, we experimentally investigate fluid–fluid displacement in a Hele–Shaw cell
where the two fluids react, upon mixing, to form solid precipitates. Under the conditions of …
where the two fluids react, upon mixing, to form solid precipitates. Under the conditions of …
Chemical garden membranes in temperature-controlled microfluidic devices
Q Wang, O Steinbock - Langmuir, 2021 - ACS Publications
Thin-walled tubes that classically form when metal salts react with sodium silicate solution
are known as chemical gardens. They share similarities with the porous, catalytic materials …
are known as chemical gardens. They share similarities with the porous, catalytic materials …
Novel regimes of calcium carbonate dissolution in micron-scale confined spaces
J Xu, MT Balhoff - Advances in Water Resources, 2022 - Elsevier
We report the discovery of novel regimes of calcium carbonate dissolution in micron-scale
confined spaces through microfluidic experiments. In the experiments, hydrochloric acid is …
confined spaces through microfluidic experiments. In the experiments, hydrochloric acid is …
Unstable miscible displacements in radial flow with chemical reactions
The effects of the $ A+ B\rightarrow C $ chemical reaction on miscible viscous fingering in a
radial source flow are analysed using linear stability theory and numerical simulations. This …
radial source flow are analysed using linear stability theory and numerical simulations. This …