Pattern selection by material aging: Modeling chemical gardens in two and three dimensions

BC Batista, AZ Morris… - Proceedings of the …, 2023 - National Acad Sciences
Chemical gardens are complex, often macroscopic, structures formed by precipitation
reactions. Their thin walls compartmentalize the system and adjust in size and shape if the …

Emergence of power-law particle size distribution in microfluidic calcium carbonate precipitation: An extended yule process with a ripening effect

J Xu, MT Balhoff - Physical Review Letters, 2023 - APS
Precipitation of calcium carbonate in bulk solutions is well known to result in a bell-shaped
or bimodal particle size distribution. However, it is unclear how the distribution behaves if …

Flow Control of Fronts by Radial Injection

F Brau, G Schuszter, A De Wit - Physical review letters, 2017 - APS
The dynamics of A+ B→ C fronts is analyzed theoretically in the presence of passive
advection when A is injected radially into B at a constant inlet flow rate Q. We compute the …

4D neutron imaging of solute transport and fluid flow in sandstone before and after mineral precipitation

P Shafabakhsh, B Cordonnier… - Water Resources …, 2024 - Wiley Online Library
In many geological systems, the porosity of rock or soil may evolve during mineral
precipitation, a process that controls fluid transport properties. Here, we investigate the use …

Self-organization of layered inorganic membranes in microfluidic devices

Q Wang, MR Bentley, O Steinbock - The Journal of Physical …, 2017 - ACS Publications
Inorganic precipitate membranes play an important role in chemobrionics and origin of life
research. They can involve a range of catalytic materials, affect crystal habits, and show …

Archimedean spirals form at low flow rates in confined chemical gardens

LAM Rocha, L Thorne, JJ Wong, JHE Cartwright… - Langmuir, 2022 - ACS Publications
We describe and study the formation of confined chemical garden patterns. At low flow rates
of injection of cobalt chloride solution into a Hele-Shaw cell filled with sodium silicate, the …

Fingering instability during mixing-driven precipitation flow

N Shahsavar, X Fu, B Zhao - Transport in Porous Media, 2024 - Springer
In this study, we experimentally investigate fluid–fluid displacement in a Hele–Shaw cell
where the two fluids react, upon mixing, to form solid precipitates. Under the conditions of …

Chemical garden membranes in temperature-controlled microfluidic devices

Q Wang, O Steinbock - Langmuir, 2021 - ACS Publications
Thin-walled tubes that classically form when metal salts react with sodium silicate solution
are known as chemical gardens. They share similarities with the porous, catalytic materials …

Novel regimes of calcium carbonate dissolution in micron-scale confined spaces

J Xu, MT Balhoff - Advances in Water Resources, 2022 - Elsevier
We report the discovery of novel regimes of calcium carbonate dissolution in micron-scale
confined spaces through microfluidic experiments. In the experiments, hydrochloric acid is …

Unstable miscible displacements in radial flow with chemical reactions

MC Kim, S Pramanik, V Sharma… - Journal of Fluid …, 2021 - cambridge.org
The effects of the $ A+ B\rightarrow C $ chemical reaction on miscible viscous fingering in a
radial source flow are analysed using linear stability theory and numerical simulations. This …