Switch chemistry at cryogenic conditions: quantum tunnelling under electric fields

O Kirshenboim, A Frenklah, S Kozuch - Chemical Science, 2021 - pubs.rsc.org
While the influence of intramolecular electric fields is a known feature in enzymes, the use of
oriented external electric fields (EEF) to enhance or inhibit molecular reactivity is a …

Theoretical Investigation of the X-ray Stark Effect in Small Molecules

A Datar, C Wright, DA Matthews - The Journal of Physical …, 2023 - ACS Publications
We have studied the Stark effect in the soft x-ray region for various small molecules by
calculating the field-dependent x-ray absorption spectra. This effect is explained in terms of …