Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …

Here we describe the discovery of a new class of C–H borylation catalysts and their use for
regioselective C–H borylation of aromatic, heteroaromatic, and aliphatic systems. The new …

The selective functionalization of C–H bonds at the arene para position is highly challenging
using transition metal catalysis. Iridium-catalyzed borylation has emerged as a leading …

The iridium‐catalysed borylation of aromatic C− H bonds has become the preferred method
for the synthesis of aromatic organoboron compounds. The reaction is highly efficient …

Over the past two decades, the C–H bond activation and functionalization reaction has been
known as a prevailing method for the construction of carbon–carbon and carbon …

Indoles are privileged heterocycles found in many biologically active pharmaceuticals and
natural products. However, the selective functionalization of the benzenoid moiety in indoles …

A highly efficient and general protocol for traceless, directed C3-selective C–H borylation of
indoles with [Ni (IMes) 2] as the catalyst is reported. Activation and borylation of N–H bonds …

The direct functionalization of C− H bonds is among the most fundamental chemical
transformations in organic synthesis. However, when the innate reactivity of the substrate …