Thiosulfonates as emerging reactants: synthesis and applications

P Mampuys, CR McElroy, JH Clark… - Advanced Synthesis …, 2020 - Wiley Online Library
The synthetic strategies towards thiosulfonates (RSO2SR1) are comprehensively reviewed
from their original discovery to recent advances. Incorporation of the green credentials of the …

Cross-Dehydrogenative C–H/S–H Coupling Reactions

A Hosseinian, S Ahmadi, FAH Nasab… - Topics in Current …, 2018 - Springer
Carbon–sulfur bond formation represents a key step in the synthesis of thioethers, which are
a common structural motif in many pharmaceutically compounds. The direct cross …

Sulfenyl chlorides: An alternative monomer feedstock from elemental sulfur for polymer synthesis

KS Kang, C Olikagu, T Lee, J Bao… - Journal of the …, 2022 - ACS Publications
A polymerization methodology is reported using sulfur monochloride (S2Cl2) as an
alternative feedstock for polymeric materials. S2Cl2 is an inexpensive petrochemical derived …

Thiol Chlorination with N-Chlorosuccinimide: HCl-Catalyzed Release of Molecular Chlorine and the Dichotomous Effects of Water

A García-Domínguez, NM West, RT Hembre… - ACS …, 2023 - ACS Publications
The kinetics of the conversion of thiophenols into sulfenyl chlorides using N-
chlorosuccinimide (NCS) in dichloromethane have been investigated by in situ 1H NMR and …

Modern synthetic approaches to phosphorus‐sulfur bond formation in organophosphorus compounds

DJ Jones, EM O'Leary… - Advanced Synthesis & …, 2020 - Wiley Online Library
Phosphorothioates, phosphonothioates, phosphinothioates and phosphonodithioates are
organophosphorus compounds with widespread application, especially in the fields of …

Natural Compounds and Their Structural Analogs in Regio- and Stereoselective Synthesis of New Families of Water-Soluble 2H,3H-[1,3]thia- and -Selenazolo[3,2-a] …

VA Potapov, RS Ishigeev, IV Shkurchenko… - Molecules, 2020 - mdpi.com
It has been found that both eugenol and isoeugenol derivatives reacted with 2-
pyridinesulfenyl and 2-pyridineselenenyl halides in a regioselective mode affording …

NMR spectroscopic characterization of polyhalodisulfides via sulfenyl chloride inverse vulcanization with sulfur monochloride

C Olikagu, VK Kumirov, JT Njardarson, MJ Hahn… - Polymer, 2024 - Elsevier
The preparation of sulfur containing polymers from inexpensive, commodity sulfur base
chemicals is an emerging field of polymer chemistry as a route to consume elemental sulfur …

Pyrazolo[1,5-a]pyridine: Recent synthetic view on crucial heterocycles

D Devi Priya, M Nandhakumar… - Synthetic …, 2020 - Taylor & Francis
Abstract Pyrazolo [1, 5-a] pyridine is one of the important core of nitrogen ring junction
heterocyclic compounds. Due to novel and uncomplicated methods, ring junction motifs …

Coupling of gem-difluorinated organozinc reagents with S-electrophiles

SS Ashirbaev, VV Levin, MI Struchkova… - Journal of Fluorine …, 2016 - Elsevier
Abstract gem-Difluorinated organozinc reagents, which were prepared by insertion of CF 2-
fragment into Csingle bondZn bond, couple with diethyl dixanthogen, di (benzothiazolyl) …

Pushing Boundaries: What's Next in Metal-Free C–H Functionalization for Sulfenylation?

P Rani, S Chahal, R Singh, J Sindhu - Topics in Current Chemistry, 2024 - Springer
The synthesis of thioether derivatives has been explored widely due to the potential
application of these derivatives in medicinal chemistry, pharmaceutical industry and material …