Elucidating the Structural Composition of an Fe–N–C Catalyst by Nuclear‐and Electron‐Resonance Techniques

S Wagner, H Auerbach, CE Tait… - Angewandte Chemie …, 2019 - Wiley Online Library
Fe–N–C catalysts are very promising materials for fuel cells and metal–air batteries. This
work gives fundamental insights into the structural composition of an Fe–N–C catalyst and …

A pyridinic Fe-N4 macrocycle models the active sites in Fe/N-doped carbon electrocatalysts

T Marshall-Roth, NJ Libretto, AT Wrobel… - Nature …, 2020 - nature.com
Iron-and nitrogen-doped carbon (Fe-NC) materials are leading candidates to replace
platinum catalysts for the oxygen reduction reaction (ORR) in fuel cells; however, their active …

Excitation of local magnetic moments by tunneling electrons

JP Gauyacq, N Lorente, FD Novaes - Progress in Surface Science, 2012 - Elsevier
The advent of milli-kelvin scanning tunneling microscopes (STM) with inbuilt magnetic fields
has opened access to the study of magnetic phenomena with atomic resolution at surfaces …

Electronic structure of bis (imino) pyridine iron dichloride, monochloride, and neutral ligand complexes: a combined structural, spectroscopic, and computational study

SC Bart, K Chłopek, E Bill, MW Bouwkamp… - Journal of the …, 2006 - ACS Publications
The electronic structure of a family of bis (imino) pyridine iron dihalide, monohalide, and
neutral ligand compounds has been investigated by spectroscopic and computational …

Synthesis, stereochemistry, and structure-related properties of. alpha.,. beta.,. gamma.,. delta.-tetraphenylporphinatoiron (II)

JP Collman, JL Hoard, N Kim, G Lang… - Journal of the American …, 1975 - ACS Publications
Reduction of chloro-a,/3, 7, 5-tetraphenylporphinatoiron (III) by bis (acetylacetonato)
chromium (II) under anaerobic conditions yields a,/3, Y,< 5-tetraphenylporphinatoiron (II), Fe …

Mössbauer spectra of inorganic compounds: Bonding and structure

GM Bancroft, RH Piatt - Advances in inorganic chemistry and …, 1972 - Elsevier
Publisher Summary Mossbauer spectroscopy can be likened to ultraviolet spectroscopy.
Both techniques employ a source of radiation, an absorber and a detector. In Mossbauer …

Spin-mixed ground state of Fe phthalocyanine and the temperature-dependent branching ratio in X-ray absorption spectroscopy

BT Thole, G Van Der Laan, PH Butler - Chemical physics letters, 1988 - Elsevier
Abstract Analysis of the Fe L 2, 3 absorption spectrum together with the temperature-
dependent susceptibility of FePC indicates a ground state which is a mixture of quintet and …

Square planar vs tetrahedral geometry in four coordinate iron (II) complexes

EJ Hawrelak, WH Bernskoetter, E Lobkovsky… - Inorganic …, 2005 - ACS Publications
The geometric preferences of a family of four coordinate, iron (II) d 6 complexes of the
general form L2FeX2 have been systematically evaluated. Treatment of Fe2 (Mes) 4 (Mes …

Highly unquenched orbital moment in textured Fe-phthalocyanine thin films

J Bartolomé, F Bartolomé, LM García, G Filoti… - Physical Review B …, 2010 - APS
X-ray magnetic circular dichroism (XMCD) measured at T= 6 K and μ 0 H= 5 T on the α-
phase Fe-phthalocyanine (FePc) textured thin films shows that the Fe 2+ ions present an …

Transition metal phthalocyanines: Insight into the electronic structure from soft x-ray spectroscopy

T Kroll, R Kraus, R Schönfelder, VY Aristov… - The Journal of …, 2012 - pubs.aip.org
Transition metal phthalocyanines (MPc's) are an interesting class of material, and their
magnetic and electronic properties are determined by the orbital occupation of the transition …