The coordination modes of (thio) semicarbazone copper (II) complexes strongly modulate the solution chemical properties and mechanism of anticancer activity

V Pósa, B Hajdu, G Tóth, O Dömötör, CR Kowol… - Journal of Inorganic …, 2022 - Elsevier
Thiosemicarbazones are promising candidates for anticancer therapy and their mechanism
of action is often linked to their metal chelating ability. In this study, five (thio) …

Triapine analogues and their copper (II) complexes: Synthesis, characterization, solution speciation, redox activity, cytotoxicity, and mR2 RNR inhibition

I Besleaga, I Stepanenko, TV Petrasheuskaya… - Inorganic …, 2021 - ACS Publications
Three new thiosemicarbazones (TSCs) HL 1–HL 3 as triapine analogues bearing a redox-
active phenolic moiety at the terminal nitrogen atom were prepared. Reactions of HL 1–HL 3 …

Synthesis, X-ray and antibacterial activity of new copper (II) thiosemicarbazone complexes derived from 4-formyl-3-hydroxy-2-naphthoic acid

N Terenti, A Lazarescu, S Shova, P Bourosh… - Inorganica Chimica …, 2024 - Elsevier
New thiosemicarbazone ligand derived from 4-formyl-3-hydroxy-2-naphthoic acid (H 3 L· CH
3 OH (1)) and their two copper (II) complexes with composition [Cu (H 2 L) Cl] 2. 2 …

[HTML][HTML] Regioselective synthesis, physicochemical properties and anticancer activity of 2-aminomethylated estrone derivatives

B Molnár, NI Kinyua, G Mótyán, P Leits, I Zupkó… - The Journal of Steroid …, 2022 - Elsevier
The unique estrogen receptor (ER)-independent antiproliferative and apoptotic activity of 2-
methoxyestradiol (2ME2) is well known, however, its use has been limited because of its …

Complex formation of an estrone-salicylaldehyde semicarbazone hybrid with copper (II) and gallium (III): Solution equilibria and biological activity

ÉA Enyedy, TV Petrasheuskaya, MA Kiss… - Journal of Inorganic …, 2021 - Elsevier
The solution chemical properties such as proton dissociation, complex formation with copper
(II) and gallium (III) ions in addition to antibacterial and antitumor activity of a novel tridentate …

Estradiol-based salicylaldehyde (thio) semicarbazones and their copper complexes with anticancer, antibacterial and antioxidant activities

TV Petrasheuskaya, F Kovács, N Igaz, A Rónavári… - Molecules, 2022 - mdpi.com
A series of novel estradiol-based salicylaldehyde (thio) semicarbazones ((T) SCs) bearing
(O, N, S) and (O, N, O) donor sets and their Cu (II) complexes were developed and …

Novel Thiosemicarbazone Derivatives from Furan‐2‐Carbaldehyde: Synthesis, Characterization, Crystal Structures, and Antibacterial, Antifungal, Antioxidant, and …

W Hernández, F Carrasco, A Vaisberg… - Journal of …, 2023 - Wiley Online Library
Ten new thiosemicarbazone derivatives, furan‐2‐carbaldehyde thiosemicarbazone (1), 3‐
methyl‐furan‐2‐carbaldehyde thiosemicarbazone (2), 5‐hydroxymethyl‐furan‐2 …

Binding models of copper (II) thiosemicarbazone complexes with human serum albumin: a speciation study

NV May, A Jancsó, ÉA Enyedy - Molecules, 2021 - mdpi.com
Copper (II) complexes of thiosemicarbazones (TSCs) often exhibit anticancer properties,
and their pharmacokinetic behavior can be affected by their interaction with blood transport …

Structural and theoretical investigations, Hirshfeld surface analysis and anti-SARS CoV-2 of nickel (II) coordination complex

S Kumar, M Choudhary - Journal of Biomolecular Structure and …, 2023 - Taylor & Francis
A nickel (II) Schiff base complex,[Ni (L)(DMF)](1), was synthesized by treating NiCl2. 6H2O
with an ONS-donor Schiff base ligand (H2L) derived from the condensation 3, 5 …

Study of novel bidentate heterocyclic amine-based metal complexes and their biological activities: cytotoxicity and antimicrobial activity evaluation

HM Fahmy, FM Abdel-Rahman, AA El-Sayed… - BMC chemistry, 2023 - Springer
Metallic antitumor drugs with heterocyclic ligands, such as novel AMI (amino methyl
imidazole) complexes [Pd (AMI) Cl2](1),[Cu (AMI) L1](2), and [Cu (AMI) L2· 2H2O](3) where …