While the implication of the aromaticity concept has been dramatically expanded to date
since its emergence in 1865, the classical [4n+ 2]/4n-electron counting protocol still plays an …

Heavier group 13/15 multiple bonds have been under investigation since the late 80s and to
date, several examples have been published, which shows the obsoleteness of the so …

Free phosphaborenes (R–P═ B–R) are PB analogues of alkynes, and their isolation is a
long-sought-after goal. Herein, we demonstrate that the combination of a π-donating and a π …

Molecular species containing multiple bonds to aluminium have long been challenging
synthetic targets. Despite recent landmark discoveries in this area, heterodinuclear Al–E …

We report the synthesis of the monomeric phosphaborene Ar* P═ B (TMP)(2)(Ar*= 2, 6-bis
(triisopropylphenyl)-3, 5-diisopropylphenyl) containing 2-coordinate phosphorus and boron …

While a stable base-free arylalumylene bearing a sterically encumbered terphenyl
substituent has been reported previously, we herein report that our attempts to form a base …

N‐containing molecules are mostly derived from ammonia (NH3). Ammonia activation has
been demonstrated for single transition metal centers as well as for low‐valent main group …

Three-membered-ring scaffolds of carbocycles, namely, cyclopropanes and cyclopropenes,
are ubiquitous in natural products and pharmaceutical molecules. These molecules exhibit a …

The reaction of bisdicyclohexylphosphinoethane (dcpe) and the subvalent MI sources [MI
(PhF) 2][pf](M= Ga+, In+;[pf]−=[Al (ORF) 4]−; RF= C (CF3) 3) yielded the salts [{M (dcpe)} …

Cycloaddition reactions of gallaphosphene L (Cl) GaPGaL 1 (L= HC [C (Me) N (2, 6‐i‐
Pr2C6H3)] 2) with carbodiimides [C (NR) 2; R= i‐Pr, Cy] and isocyanates [RNCO; R= Et, i …