Microstructural and dynamical heterogeneities in ionic liquids
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …
molecular symmetry and charge delocalization. The versatility in combining varied cation …
Dynamics of a room temperature ionic liquid in supported ionic liquid membranes vs the bulk liquid: 2D IR and polarized IR pump–probe experiments
Supported ionic liquid membranes (SILMs) are membranes that have ionic liquids
impregnated in their pores. SILMs have been proposed for advanced carbon capture …
impregnated in their pores. SILMs have been proposed for advanced carbon capture …
Carbon Dioxide in a Supported Ionic Liquid Membrane: Structural and Rotational Dynamics Measured with 2D IR and Pump–Probe Experiments
Supported ionic liquid membranes (SILMs) are porous membranes impregnated with ionic
liquids (ILs) and used as advanced carbon capture materials. Here, two-dimensional …
liquids (ILs) and used as advanced carbon capture materials. Here, two-dimensional …
Does variation in composition affect dynamics when approaching the eutectic composition?
Deep eutectic solvent is a mixture of two or more components, mixed in a certain molar ratio,
such that the mixture melts at a temperature lower than individual substances. In this work …
such that the mixture melts at a temperature lower than individual substances. In this work …
Does viscosity drive the dynamics in an alcohol-based deep eutectic solvent?
S Chatterjee, SH Deshmukh… - The Journal of Physical …, 2022 - ACS Publications
Deep eutectic solvents, consisting of heterogeneous nanodomains of hydrogen-bonded
networks, have evolved into a range of viscous fluids that find applications in several fields …
networks, have evolved into a range of viscous fluids that find applications in several fields …
Dynamics in a room-temperature ionic liquid from the cation perspective: 2D IR vibrational echo spectroscopy
The dynamics of the room-temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium bis
(trifluoromethylsulfonyl) imide (BmimNTf2) were investigated with two-dimensional infrared …
(trifluoromethylsulfonyl) imide (BmimNTf2) were investigated with two-dimensional infrared …
An “iceberg” coating preserves bulk hydration dynamics in aqueous PEG solutions
KR Daley, KJ Kubarych - The Journal of Physical Chemistry B, 2017 - ACS Publications
Ultrafast picosecond time scale two-dimensional infrared (2D-IR) spectroscopy of a new
water-soluble transition metal complex acting as a vibrational probe shows that over a range …
water-soluble transition metal complex acting as a vibrational probe shows that over a range …
Vibrational relaxation of carbon dioxide in water
J Gleim, J Lindner, P Vöhringer - The Journal of Chemical Physics, 2022 - pubs.aip.org
The dynamics of vibrational relaxation of carbon dioxide in water has been studied using
femtosecond mid-infrared pump–probe spectroscopy with excitation of the anti-symmetric …
femtosecond mid-infrared pump–probe spectroscopy with excitation of the anti-symmetric …
Generation of High-Lying Vibrational States in Carbon Dioxide through Coherent Ladder Climbing
I Morichika, H Tsusaka, S Ashihara - The Journal of Physical …, 2024 - ACS Publications
Mid-infrared laser excitation of molecules into high-lying vibrational states offers a novel
route to realize controlled ground-state chemistry. Here we successfully demonstrate …
route to realize controlled ground-state chemistry. Here we successfully demonstrate …
Dynamics of dicyanamide in ionic liquids is dominated by local interactions
The dynamics of probe molecules is commonly used to investigate the structural dynamics of
room-temperature ionic liquids; however, the extent to which this dynamics reflects the …
room-temperature ionic liquids; however, the extent to which this dynamics reflects the …