Bioinspired chiral inorganic nanomaterials
From small molecules to entire organisms, evolution has refined biological structures at the
nanoscale, microscale and macroscale to be chiral—that is, mirror dissymmetric. Chirality …
nanoscale, microscale and macroscale to be chiral—that is, mirror dissymmetric. Chirality …
Calcium Carbonate Precipitation for CO2 Storage and Utilization: A Review of the Carbonate Crystallization and Polymorphism
The transformation of CO2 into a precipitated mineral carbonate through an ex situ mineral
carbonation route is considered a promising option for carbon capture and storage (CCS) …
carbonation route is considered a promising option for carbon capture and storage (CCS) …
A hydrated crystalline calcium carbonate phase: Calcium carbonate hemihydrate
Z Zou, WJEM Habraken, G Matveeva, ACS Jensen… - Science, 2019 - science.org
As one of the most abundant materials in the world, calcium carbonate, CaCO3, is the main
constituent of the skeletons and shells of various marine organisms. It is used in the cement …
constituent of the skeletons and shells of various marine organisms. It is used in the cement …
Nucleation of metastable aragonite CaCO3 in seawater
Predicting the conditions in which a compound adopts a metastable structure when it
crystallizes out of solution is an unsolved and fundamental problem in materials synthesis …
crystallizes out of solution is an unsolved and fundamental problem in materials synthesis …
Designing solid materials from their solute state: a shift in paradigms toward a holistic approach in functional materials chemistry
“Non-classical” notions consider formation pathways of crystalline materials where larger
species than monomeric chemical constituents, ie, ions or single molecules, play crucial …
species than monomeric chemical constituents, ie, ions or single molecules, play crucial …
Chiral acidic amino acids induce chiral hierarchical structure in calcium carbonate
W Jiang, MS Pacella, D Athanasiadou, V Nelea… - Nature …, 2017 - nature.com
Chirality is ubiquitous in biology, including in biomineralization, where it is found in many
hardened structures of invertebrate marine and terrestrial organisms (for example, spiralling …
hardened structures of invertebrate marine and terrestrial organisms (for example, spiralling …
The Raman spectrum of CaCO3 polymorphs calcite and aragonite: A combined experimental and computational study
M De La Pierre, C Carteret, L Maschio… - The Journal of …, 2014 - pubs.aip.org
Powder and single crystal Raman spectra of the two most common phases of calcium
carbonate are calculated with ab initio techniques (using a “hybrid” functional and a …
carbonate are calculated with ab initio techniques (using a “hybrid” functional and a …
A review of the structures of vaterite: the impossible, the possible, and the likely
AG Christy - Crystal Growth & Design, 2017 - ACS Publications
The importance of the metastable vaterite form of CaCO3 is increasingly appreciated as an
intermediate between amorphous calcium carbonate and more stable crystalline …
intermediate between amorphous calcium carbonate and more stable crystalline …
A Molecular‐Scale Understanding of Misorientation Toughening in Corals and Seashells
AJ Lew, CA Stifler, A Tits, CA Schmidt… - Advanced …, 2023 - Wiley Online Library
Biominerals are organic–mineral composites formed by living organisms. They are the
hardest and toughest tissues in those organisms, are often polycrystalline, and their …
hardest and toughest tissues in those organisms, are often polycrystalline, and their …
[HTML][HTML] The underlying role of sodium tripolyphosphate on the cementitious mechanism of calcium carbonate binder
Calcium carbonate binder is well-known to reduce the carbon footprint and brings great
economic and environmental benefits. However, the cementitious mechanism is unclear due …
economic and environmental benefits. However, the cementitious mechanism is unclear due …