Scanning probe microscopy in probing low-dimensional carbon-based nanostructures and nanomaterials

C Zhang, Z Yi, W Xu - Materials Futures, 2022 - iopscience.iop.org
Carbon, as an indispensable chemical element on Earth, has diverse covalent bonding
ability, which enables construction of extensive pivotal carbon-based structures in multiple …

On-surface synthesis of graphene nanoribbons with atomically precise structural heterogeneities and on-site characterizations

R Yin, Z Wang, S Tan, C Ma, B Wang - ACS nano, 2023 - ACS Publications
Graphene nanoribbons (GNRs) are strips of graphene, with widths of a few nanometers, that
are promising candidates for future applications in nanodevices and quantum information …

Magnetic interactions in substitutional core-doped graphene nanoribbons

ECH Wen, PH Jacobse, J Jiang, Z Wang… - Journal of the …, 2022 - ACS Publications
The design of a spin imbalance within the crystallographic unit cell of bottom-up engineered
1D graphene nanoribbons (GNRs) gives rise to nonzero magnetic moments within each cell …

Preparation, bandgap engineering, and performance control of graphene nanoribbons

H Luo, G Yu - Chemistry of Materials, 2022 - ACS Publications
Graphene nanoribbons (GNRs) exhibit a series of essential electronic properties, especially
in establishing tunable bandgaps. The bandgaps are determined by structural features of …

A Heterometallic Porphyrin Dimer as a Potential Quantum Gate: Magneto‐Structural Correlations and Spin Coherence Properties

D Ranieri, A Privitera, F Santanni… - Angewandte …, 2023 - Wiley Online Library
In the development of two‐qubit quantum gates, precise control over the intramolecular spin‐
spin interaction between molecular spin units plays a pivotal role. A weak but measurable …

Backbone engineering of monodisperse conjugated polymers via integrated iterative binomial synthesis

J Yin, S Choi, D Pyle, JR Guest… - Journal of the American …, 2023 - ACS Publications
Synthesis of sequence-defined monodisperse π-conjugated polymers with versatile
backbones remains a substantial challenge. Here we report the development of an …

Programmable fabrication of monodisperse graphene nanoribbons via deterministic iterative synthesis

J Yin, PH Jacobse, D Pyle, Z Wang… - Journal of the …, 2022 - ACS Publications
While enormous progress has been achieved in synthesizing atomically precise graphene
nanoribbons (GNRs), the preparation of GNRs with a fully predetermined length and …

Synthesis and characterization of low-dimensional N-heterocyclic carbene lattices

B Qie, Z Wang, J Jiang, Z Zhang, PH Jacobse, J Lu… - Science, 2024 - science.org
The covalent interaction of N-heterocyclic carbenes (NHCs) with transition metal atoms
gives rise to distinctive frontier molecular orbitals (FMOs). These emergent electronic states …

Five-Membered Rings Create Off-Zero Modes in Nanographene

PH Jacobse, MC Daugherty, K Cernevics, Z Wang… - ACS …, 2023 - ACS Publications
The low-energy electronic structure of nanographenes can be tuned through zero-energy π-
electron states, typically referred to as zero-modes. Customizable electronic and magnetic …

Pseudo-atomic orbital behavior in graphene nanoribbons with four-membered rings

PH Jacobse, Z Jin, J Jiang, S Peurifoy, Z Yue… - Science …, 2021 - science.org
The incorporation of nonhexagonal rings into graphene nanoribbons (GNRs) is an effective
strategy for engineering localized electronic states, bandgaps, and magnetic properties …