Carboxylates of rare earth elements
R Janicki, A Mondry, P Starynowicz - Coordination Chemistry Reviews, 2017 - Elsevier
Rare earth carboxylates constitute an enormous group of compounds with various structures
and properties. The carboxylate group may be bonded to the metal cations in several ways …
and properties. The carboxylate group may be bonded to the metal cations in several ways …
Chemical and redox speciation of uranyl with three environmentally relevant bifunctional chelates: multi-technique approach combined with theoretical estimations
A Srivastava, RMR Dumpala, P Kumar… - Inorganic …, 2022 - ACS Publications
Carbon and phosphorous are two primary elements common to the bio-geosphere and are
omnipresent in both biotic and abiotic arenas. Phosphonate and carboxylate are considered …
omnipresent in both biotic and abiotic arenas. Phosphonate and carboxylate are considered …
Elucidation of the sorbent role in sorption thermodynamics of uranium (VI) on goethite
S Kumar, RMR Dumpala, A Chandane… - … Science: Processes & …, 2022 - pubs.rsc.org
The sorption process of radionuclides, often conducted at ambient temperature, shows
significant sensitivity to the surrounding temperature. Prediction of fate and transport in the …
significant sensitivity to the surrounding temperature. Prediction of fate and transport in the …
Reduction in coordination number of Eu (III) on complexation with pyrazine mono-and di-carboxylates in aqueous medium
RMR Dumpala, A Boda, P Kumar, N Rawat… - Inorganic …, 2019 - ACS Publications
The denticity, flexibility, and steric hindrance of the ligand are key factors in deciding the
mode and number of coordination around a metal ion on complex formation. The …
mode and number of coordination around a metal ion on complex formation. The …
Stabilization of uranyl (V) by dipicolinic acid in aqueous medium
Preparation of a stable U (V) complex in an aqueous medium is a challenging task owing to
its disproportionation nature (conversion into more stable U (VI) and U (IV) species) and …
its disproportionation nature (conversion into more stable U (VI) and U (IV) species) and …
Failure of ESI spectra to represent metal-complex solution composition: a study of lanthanide–carboxylate complexes
LW McDonald IV, JA Campbell, SB Clark - Analytical chemistry, 2014 - ACS Publications
Electrospray ionization-mass spectrometry (ESI-MS) shows great promise as a rapid method
to identify metal–ligand complexes in solution. However, its application for quantitative …
to identify metal–ligand complexes in solution. However, its application for quantitative …
Protonation of phosphonocarboxylates in aqueous medium: an experimental and theoretical investigation
RMR Dumpala, A Srivastava, S Sharma… - Journal of Chemical & …, 2022 - ACS Publications
Phosphonates and carboxylates are two primitive functional groups omnipresent in nature,
and they act as good chelators for metal ion binding. These two functional groups are …
and they act as good chelators for metal ion binding. These two functional groups are …
Experimental and DFT studies on complexation of uranyl with N-(2-Hydroxyethyl) iminodiacetic acid in aqueous medium
S Sharma, RMR Dumpalan, N Rawat - Inorganica Chimica Acta, 2020 - Elsevier
The nuclear decontaminating agents such as ethylenediamminetetraacetic acid (EDTA),
picolinic acid, nitrilotriacetic acid (NTA) and citric acid are co-disposed with the nuclear …
picolinic acid, nitrilotriacetic acid (NTA) and citric acid are co-disposed with the nuclear …
Thorium Complexation with Aliphatic and Aromatic Hydroxycarboxylates: A Combined Experimental and Theoretical Study
P Kumar, RMR Dumpala, VM Telmore, B Sadhu… - ACS …, 2024 - ACS Publications
Hydroxycarboxylic acids, viz., α-hydroxyisobutyric acid (HIBA) and mandelic acid (MA), have
been widely employed as eluents for inner transition metal separation studies. Both …
been widely employed as eluents for inner transition metal separation studies. Both …
Enhanced luminescence of tris (carboxylato) uranyl (vi) complexes and energy transfer to Eu (iii): a combined spectroscopic and theoretical investigation
S Kumar, S Maji, K Sundararajan - Dalton Transactions, 2022 - pubs.rsc.org
Complex formation between uranyl and carboxylate ligands (benzoate, nicotinate and
isonicotinate) has been studied extensively by absorption and luminescence spectroscopy …
isonicotinate) has been studied extensively by absorption and luminescence spectroscopy …